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In the hydrodeoxygenation (HDO) of alkylphenols, hydroxyl groups must be removed while avoiding the hydrogenation of the aromatic ring. Here, the HDO of propylphenols is studied using a Pt\/Nb<jats:sub>2<\/jats:sub>O<jats:sub>5<\/jats:sub> catalyst and <jats:italic>n<\/jats:italic>\u2010tetradecane solvent. HDO experiments are performed using different reaction conditions of batch residence time (0\u2013161 min g<jats:sub>cat<\/jats:sub> g<jats:sub>reactant<\/jats:sub><jats:sup>\u22121<\/jats:sup>), pressure (20\u201330 bar H<jats:sub>2<\/jats:sub>), and temperature (300\u2013375 \u00b0C). HDO is studied with <jats:italic>ortho\u2010<\/jats:italic>, <jats:italic>meta\u2010<\/jats:italic>, and <jats:italic>para<\/jats:italic>\u2010propylphenol. The influence of vapor\u2013liquid equilibrium and chemical equilibrium are assessed using thermodynamic calculations. Almost full deoxygenation is attained in the experiments; the main products are propylbenzene and propylcyclohexane. The study finds that, of the isomers, 4\u2010propylphenol is the most favorable for forming propylbenzene (77% maximum selectivity), whereas 2\u2010propylphenol is the least favorable (55% maximum selectivity). Additionally, the reactivity of propylbenzene in the test conditions is detrimental to its selectivity after 5 min g<jats:sub>cat<\/jats:sub> g<jats:sub>reactant<\/jats:sub><jats:sup>\u22121<\/jats:sup>. Finally, the temperature at which the process favors propylbenzene is found to shift as a function of pressure; at 20 bar, propylbenzene is favored at 350 \u00b0C and at 30 bar, it is favored at 375 \u00b0C.<\/jats:p>","DOI":"10.1002\/adsu.201900140","type":"journal-article","created":{"date-parts":[[2020,4,27]],"date-time":"2020-04-27T05:24:16Z","timestamp":1587965056000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Hydrodeoxygenation of Propylphenols on a Niobia\u2010Supported Platinum Catalyst: <i>Ortho<\/i>, <i>Meta<\/i>, <i>Para<\/i> Isomerism, Reaction Conditions, and Phase Equilibria"],"prefix":"10.1002","volume":"4","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-8357-201X","authenticated-orcid":false,"given":"Jos\u00e9 Luis","family":"Gonz\u00e1lez Escobedo","sequence":"first","affiliation":[{"name":"Aalto University Department of Chemical and Metallurgical Engineering  P.O. 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