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Through strategic isotope labeling, all nonhydrogen atoms were distinct from one another, and allowed an unprecedented level of understanding of the dominant reaction pathways. All combinations of isotope\u2010 and non\u2010isotope\u2010labeled atoms were detected in the products, thus there are multiple pathways involved in H<jats:sub>2<\/jats:sub>, CO, CO<jats:sub>2<\/jats:sub>, CH<jats:sub>4<\/jats:sub>, C<jats:sub>2<\/jats:sub>H<jats:sub>4<\/jats:sub>, and C<jats:sub>2<\/jats:sub>H<jats:sub>6<\/jats:sub> product formation. Both the recombination of C species on the surface of the catalyst and preservation of the C\u2212C bond within ethanol are responsible for C<jats:sub>2<\/jats:sub> product formation. Ethylene is not detected until conversion drops below 100\u2009% at <jats:italic>t<\/jats:italic>=1.25\u2005h. Also, quantitatively, 57\u2009% of the observed ethylene is formed directly through ethanol dehydration. Finally there is clear evidence to show that oxygen in the SiO<jats:sub>2<\/jats:sub>\u2010ZrO<jats:sub>2<\/jats:sub> support constitutes 10\u2009% of the CO formed during the reaction.<\/jats:p>","DOI":"10.1002\/ange.201604388","type":"journal-article","created":{"date-parts":[[2016,8,3]],"date-time":"2016-08-03T15:31:19Z","timestamp":1470238279000},"page":"10808-10813","source":"Crossref","is-referenced-by-count":2,"title":["Mechanistic Insights into Catalytic Ethanol Steam Reforming Using Isotope\u2010Labeled Reactants"],"prefix":"10.1002","volume":"128","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-3345-2778","authenticated-orcid":false,"given":"Stephen","family":"Crowley","sequence":"first","affiliation":[{"name":"Department of Chemical Engineering City College of the City University of New York  New York NY 10031 USA"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8951-9348","authenticated-orcid":false,"given":"Marco J.","family":"Castaldi","sequence":"additional","affiliation":[{"name":"Department of Chemical Engineering City College of the City University of New York  New York NY 10031 USA"}]}],"member":"311","published-online":{"date-parts":[[2016,8,3]]},"reference":[{"volume-title":"Heterogeneous Catalysis: Principles and Applications","year":"1987","author":"Bond G.","key":"e_1_2_2_1_1"},{"key":"e_1_2_2_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/ie049202k"},{"key":"e_1_2_2_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0920-5861(02)00232-8"},{"key":"e_1_2_2_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ces.2011.07.024"},{"key":"e_1_2_2_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijhydene.2013.12.001"},{"volume-title":"The World Market for Bio-Based Chemicals","year":"2012","author":"Deschamps N.","key":"e_1_2_2_6_1"},{"key":"e_1_2_2_7_1","doi-asserted-by":"crossref","DOI":"10.1021\/bk-2011-1063.ch001","volume-title":"Renewable and Sustainable Polymers","author":"Smith P. 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