{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,9,20]],"date-time":"2025-09-20T20:21:25Z","timestamp":1758399685284,"version":"3.37.3"},"reference-count":33,"publisher":"Wiley","issue":"18","license":[{"start":{"date-parts":[[2019,2,14]],"date-time":"2019-02-14T00:00:00Z","timestamp":1550102400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100003006","name":"Eidgen\u00f6ssische Technische Hochschule Z\u00fcrich","doi-asserted-by":"publisher","award":["ETH-04 16-1"],"award-info":[{"award-number":["ETH-04 16-1"]}],"id":[{"id":"10.13039\/501100003006","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100005380","name":"Bundesamt f\u00fcr Energie","doi-asserted-by":"publisher","award":["SI\/501269-01"],"award-info":[{"award-number":["SI\/501269-01"]}],"id":[{"id":"10.13039\/501100005380","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003825","name":"Magyar Tudom\u00e1nyos Akad\u00e9mia","doi-asserted-by":"publisher","award":["124068"],"award-info":[{"award-number":["124068"]}],"id":[{"id":"10.13039\/501100003825","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angewandte Chemie"],"published-print":{"date-parts":[[2019,4,23]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Die Produktzusammensetzung der direkten Alkanfunktionalisierung durch Oxychlorierung h\u00e4ngt stark von dem verwendeten Halogen ab. Wir zeigen, dass die \u00fcberragende Olefinselektivit\u00e4t \u00fcber Eisenphosphatkatalysatoren in Oxychlorierungen eine Konsequenz einer oberfl\u00e4chengebundenen Reaktion ist. Im Unterschied dazu folgt die Alkanaktivierung bei der Oxybromierung einer Radikalkettenreaktion in der Gasphase, wobei ein Gemisch aus Alkylbromid, Cracking\u2010 und Verbrennungsprodukten entsteht. Die Katalysatoroberfl\u00e4chenchlorierung und die Identifikation von Gasphasenradikalen werden unter Operando\u2010Bedingungen durch Einsatz verschiedener Methoden mit der katalytischen Leistung korreliert, der es erlaubt, kinetische Untersuchungen mit fortschrittlichen Charakterisierungstechniken, z.\u2009B. Prompt\u2010Gamma\u2010Aktivierungsanalyse und Photoelektronen\u2010Photoion\u2010Koinzidenzspektroskopie, zu vereinen. Die gleichzeitige Erkl\u00e4rung der Gasphasen\u2010 und Oberfl\u00e4chenanteile durch Dichtefunktionaltheorie zeigt, dass die molekularen Auswirkungen von Chlor entscheidend f\u00fcr die starken Selektivit\u00e4tsunterschiede sind. Diese Ergebnisse liefern eine Strategie, die es erm\u00f6glicht, ein detailliertes mechanistisches Bild eines komplexen Reaktionsnetzwerks zu zeichnen.<\/jats:p>","DOI":"10.1002\/ange.201811669","type":"journal-article","created":{"date-parts":[[2019,1,15]],"date-time":"2019-01-15T18:53:35Z","timestamp":1547578415000},"page":"5935-5940","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":8,"title":["Halogenbedingte Oberfl\u00e4chenbindung steuert die selektive Alkanfunktionalisierung zu Olefinen"],"prefix":"10.1002","volume":"131","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-7062-8720","authenticated-orcid":false,"given":"Guido","family":"Zichittella","sequence":"first","affiliation":[{"name":"Institut f\u00fcr Chemie- und Bioingenieurwissenschaften Department f\u00fcr Chemie und Angewandte Biowissenschaften ETH Z\u00fcrich  Vladimir-Prelog-Weg 1 8093 Z\u00fcrich Schweiz"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0943-561X","authenticated-orcid":false,"given":"Matthias","family":"Scharfe","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Chemie- und Bioingenieurwissenschaften Department f\u00fcr Chemie und Angewandte Biowissenschaften ETH Z\u00fcrich  Vladimir-Prelog-Weg 1 8093 Z\u00fcrich Schweiz"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9468-3142","authenticated-orcid":false,"given":"Bego\u00f1a","family":"Pu\u00e9rtolas","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Chemie- und Bioingenieurwissenschaften Department f\u00fcr Chemie und Angewandte Biowissenschaften ETH Z\u00fcrich  Vladimir-Prelog-Weg 1 8093 Z\u00fcrich Schweiz"}]},{"given":"Vladimir","family":"Paunovi\u0107","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Chemie- und Bioingenieurwissenschaften Department f\u00fcr Chemie und Angewandte Biowissenschaften ETH Z\u00fcrich  Vladimir-Prelog-Weg 1 8093 Z\u00fcrich Schweiz"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1251-4549","authenticated-orcid":false,"given":"Patrick","family":"Hemberger","sequence":"additional","affiliation":[{"name":"Labor f\u00fcr Femtochemie und Synchrotronstrahlung Paul Scherrer Institut  5232 Villigen Schweiz"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2742-1051","authenticated-orcid":false,"given":"Andras","family":"Bodi","sequence":"additional","affiliation":[{"name":"Labor f\u00fcr Femtochemie und Synchrotronstrahlung Paul Scherrer Institut  5232 Villigen Schweiz"}]},{"given":"L\u00e1szl\u00f3","family":"Szentmikl\u00f3si","sequence":"additional","affiliation":[{"name":"Nuklearanalyse und Radiographie Department, Zentrum f\u00fcr Energieforschung Ungarische Akademie der Wissenschaften  Konkoly-Thege Mikl\u00f3si \u00fat 29\u201333 1121 Budapest Ungarn"}]},{"given":"N\u00faria","family":"L\u00f3pez","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Chemische Forschung Katalonien Barcelona Institut f\u00fcr Wissenschaft und Technologie  Av. Pa\u00efsos Catalans 16 43007 Tarragona Spanien"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5805-7355","authenticated-orcid":false,"given":"Javier","family":"P\u00e9rez\u2010Ram\u00edrez","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Chemie- und Bioingenieurwissenschaften Department f\u00fcr Chemie und Angewandte Biowissenschaften ETH Z\u00fcrich  Vladimir-Prelog-Weg 1 8093 Z\u00fcrich Schweiz"}]}],"member":"311","published-online":{"date-parts":[[2019,2,14]]},"reference":[{"key":"e_1_2_2_1_1","unstructured":"\u00a0"},{"key":"e_1_2_2_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.6b00551"},{"key":"e_1_2_2_3_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1226840"},{"key":"e_1_2_2_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201006424"},{"key":"e_1_2_2_4_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201006424"},{"key":"e_1_2_2_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr5002436"},{"key":"e_1_2_2_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b08707"},{"key":"e_1_2_2_7_2","doi-asserted-by":"publisher","DOI":"10.1007\/s10562-014-1417-z"},{"key":"e_1_2_2_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.6b00428"},{"key":"e_1_2_2_9_1","unstructured":"\u00a0"},{"key":"e_1_2_2_10_2","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.201200966"},{"key":"e_1_2_2_11_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.cattod.2007.05.009"},{"key":"e_1_2_2_12_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201310632"},{"key":"e_1_2_2_12_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201310632"},{"key":"e_1_2_2_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/cs5003417"},{"key":"e_1_2_2_14_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-018-0071-z"},{"key":"e_1_2_2_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201706624"},{"key":"e_1_2_2_15_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201706624"},{"key":"e_1_2_2_16_1","unstructured":"\u00a0"},{"key":"e_1_2_2_17_2","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.2522"},{"key":"e_1_2_2_18_2","doi-asserted-by":"publisher","DOI":"10.1039\/C8CY00122G"},{"key":"e_1_2_2_19_2","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.201701632"},{"key":"e_1_2_2_20_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cattod.2011.04.020"},{"key":"e_1_2_2_21_1","doi-asserted-by":"publisher","DOI":"10.1007\/978-0-387-23359-8"},{"key":"e_1_2_2_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/ac800882k"},{"key":"e_1_2_2_23_1","unstructured":"\u00a0"},{"key":"e_1_2_2_24_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.4965428"},{"key":"e_1_2_2_25_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp510319b"},{"key":"e_1_2_2_26_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.4861175"},{"key":"e_1_2_2_27_2","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms15946"},{"key":"e_1_2_2_28_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp501117n"},{"key":"e_1_2_2_29_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11244-008-9102-3"},{"key":"e_1_2_2_30_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41563-018-0165-7"}],"container-title":["Angewandte Chemie"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fange.201811669","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/ange.201811669","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/ange.201811669","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/ange.201811669","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,9,10]],"date-time":"2023-09-10T12:31:05Z","timestamp":1694349065000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/ange.201811669"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2019,2,14]]},"references-count":33,"journal-issue":{"issue":"18","published-print":{"date-parts":[[2019,4,23]]}},"alternative-id":["10.1002\/ange.201811669"],"URL":"https:\/\/doi.org\/10.1002\/ange.201811669","archive":["Portico"],"relation":{},"ISSN":["0044-8249","1521-3757"],"issn-type":[{"type":"print","value":"0044-8249"},{"type":"electronic","value":"1521-3757"}],"subject":[],"published":{"date-parts":[[2019,2,14]]},"assertion":[{"value":"2018-10-10","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2019-02-14","order":2,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}]}}