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However, selective ion transport and\/or exchange in the crystalline state is rare, and to the best of our knowledge, such a process has not been successfully combined with changes in the physical properties of a material. Herein, by soaking single crystals of Li<jats:sub>2<\/jats:sub>([18]crown\u20106)<jats:sub>3<\/jats:sub>[Ni(dmit)<jats:sub>2<\/jats:sub>]<jats:sub>2<\/jats:sub>(H<jats:sub>2<\/jats:sub>O)<jats:sub>4<\/jats:sub> (<jats:bold>1<\/jats:bold>) in an aqueous solution containing K<jats:sup>+<\/jats:sup>, we succeeded in complete ion exchange of the Li<jats:sup>+<\/jats:sup> ions in <jats:bold>1<\/jats:bold> with K<jats:sup>+<\/jats:sup> ions in the solution, while maintaining the crystalline state of the material. This ion exchange with K<jats:sup>+<\/jats:sup> was selectively conducted even in mixed solutions containing K<jats:sup>+<\/jats:sup> as well as Na<jats:sup>+<\/jats:sup>\/Li<jats:sup>+<\/jats:sup>. Furthermore, remarkable changes in the physical properties of <jats:bold>1<\/jats:bold> resulted from the ion exchange. Our finding enables not only the realization of selective ion permeability but also the development of highly sensitive biosensors and futuristic ion exchange agents, for example.<\/jats:p>","DOI":"10.1002\/ange.201813709","type":"journal-article","created":{"date-parts":[[2019,1,24]],"date-time":"2019-01-24T18:50:56Z","timestamp":1548355856000},"page":"4213-4216","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Selective Ion Exchange in Supramolecular Channels in the Crystalline State"],"prefix":"10.1002","volume":"131","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-1125-4420","authenticated-orcid":false,"given":"Katsuya","family":"Ichihashi","sequence":"first","affiliation":[{"name":"Department of Chemistry Graduate School of Science Hiroshima University  1-3-1 Kagamiyama Higashi-Hiroshima 739-8526 Japan"}]},{"given":"Daisuke","family":"Konno","sequence":"additional","affiliation":[{"name":"Department of Chemistry Graduate School of Science Hiroshima University  1-3-1 Kagamiyama Higashi-Hiroshima 739-8526 Japan"}]},{"given":"Kseniya Yu.","family":"Maryunina","sequence":"additional","affiliation":[{"name":"Department of Chemistry Graduate School of Science Hiroshima University  1-3-1 Kagamiyama Higashi-Hiroshima 739-8526 Japan"},{"name":"Chirality Research Center (CResCent) Hiroshima University  1-3-1 Kagamiyama Higashi-Hiroshima 739-8526 Japan"}]},{"given":"Katsuya","family":"Inoue","sequence":"additional","affiliation":[{"name":"Department of Chemistry Graduate School of Science Hiroshima University  1-3-1 Kagamiyama Higashi-Hiroshima 739-8526 Japan"},{"name":"Chirality Research Center (CResCent) Hiroshima University  1-3-1 Kagamiyama Higashi-Hiroshima 739-8526 Japan"},{"name":"Institute for Advanced Materials Research Hiroshima University  1-3-1 Kagamiyama Higashi-Hiroshima 739-8526 Japan"}]},{"given":"Kazuhiro","family":"Toyoda","sequence":"additional","affiliation":[{"name":"Faculty of Environmental Earth Science Hokkaido University  N10W5, Kita-ku Sapporo 060-0810 Japan"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8498-0936","authenticated-orcid":false,"given":"Shogo","family":"Kawaguchi","sequence":"additional","affiliation":[{"name":"Japan Synchrotron Radiation Research Institute (JASRI) SPring-8  1-1-1 Kouto Sayo 679-5198 Japan"}]},{"given":"Yoshiki","family":"Kubota","sequence":"additional","affiliation":[{"name":"Department of Physical Science Graduate School of Science Osaka Prefecture University  1-1 Gakuen-cho, Naka-ku Sakai 599-8531 Japan"}]},{"given":"Yoko","family":"Tatewaki","sequence":"additional","affiliation":[{"name":"Department of Applied Chemistry Graduate School of Engineering Tokyo University of Agriculture and Technology  2-24-16 Nakacho Koganei 184-8588 Japan"}]},{"given":"Tomoyuki","family":"Akutagawa","sequence":"additional","affiliation":[{"name":"Institute of Multidisciplinary Research for Advanced Materials Tohoku University  2-1-1 Katahira Aoba-ku Sendai 980-8577 Japan"}]},{"given":"Takayoshi","family":"Nakamura","sequence":"additional","affiliation":[{"name":"Research Institute for Electronic Science Hokkaido University  N20W10, Kita-ku Sapporo 001-0020 Japan"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4030-786X","authenticated-orcid":false,"given":"Sadafumi","family":"Nishihara","sequence":"additional","affiliation":[{"name":"Department of Chemistry Graduate School of Science Hiroshima University  1-3-1 Kagamiyama Higashi-Hiroshima 739-8526 Japan"},{"name":"Chirality Research Center (CResCent) Hiroshima University  1-3-1 Kagamiyama Higashi-Hiroshima 739-8526 Japan"},{"name":"Institute for Advanced Materials Research Hiroshima University  1-3-1 Kagamiyama Higashi-Hiroshima 739-8526 Japan"}]}],"member":"311","published-online":{"date-parts":[[2019,1,30]]},"reference":[{"key":"e_1_2_2_1_1","unstructured":"\u00a0"},{"key":"e_1_2_2_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar00028a009"},{"volume-title":"Lehninger Principles of Biochemistry","year":"2004","author":"Nelson D. 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