{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,14]],"date-time":"2026-10-14T11:53:58Z","timestamp":1791978838421,"version":"4.4.0"},"reference-count":48,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,10,14]],"date-time":"2026-10-14T00:00:00Z","timestamp":1791936000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,10,14]],"date-time":"2026-10-14T00:00:00Z","timestamp":1791936000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Adv Funct Materials"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Practical LiNi\n                    <jats:sub>0.8<\/jats:sub>\n                    Co\n                    <jats:sub>0.1<\/jats:sub>\n                    Mn\n                    <jats:sub>0.1<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    ||graphite pouch cells suffer rapid degradation under thermal stress because liquid\u2010phase impurity reactions, electrode interphase failure, and cathode\u2013anode cross\u2010talk are tightly coupled. However, most strategies are designed to address either impurity chemistry or interphase chemistry, leaving the amplified cross\u2010talk between electrolyte degradation and electrode failure unresolved. Here, we propose a cross\u2010phase impurity\u2013interphase regulation strategy using p\u2010Phenylenebis(dimethylvinylsilane) (PDVS) for LiNi\n                    <jats:sub>0.8<\/jats:sub>\n                    Co\n                    <jats:sub>0.1<\/jats:sub>\n                    Mn\n                    <jats:sub>0.1<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    ||graphite pouch cells. The vinyl\u2010dimethylsilyl groups endow PDVS with synchronized liquid\u2010phase scavenging and solid\u2010phase interphase\u2010forming capability. In the liquid phase, PDVS acts as an impurity scavenger, lowering HF from 90.88 ppm to 29.44 ppm while reducing residual H\n                    <jats:sub>2<\/jats:sub>\n                    O from 10.65 to 8.45 ppm, thereby suppressing LiPF\n                    <jats:sub>6<\/jats:sub>\n                    hydrolysis and reducing the accumulation of corrosive by\u2010products. At the solid interfaces, PDVS preferentially participates in interfacial reactions to construct Si\u2010containing cathode\u2010electrolyte interphase and solid\u2010electrolyte interphase on the Ni\u2010rich cathode and graphite anode, mitigating electrolyte decomposition, gas evolution, transition\u2010metal crossover, and resistance growth. Consequently, 2 Ah LiNi\n                    <jats:sub>0.8<\/jats:sub>\n                    Co\n                    <jats:sub>0.1<\/jats:sub>\n                    Mn\n                    <jats:sub>0.1<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    ||graphite pouch cells retain 92.81% capacity after 304 cycles at 45\u00b0C, show reduced swelling during 60\u00b0C storage, and maintain 86.5% capacity after over 1620 cycles at 25\u00b0C. This work establishes cross\u2010phase impurity\u2013interphase regulation as a manufacturing\u2010compatible electrolyte design principle for thermally durable Ni\u2010rich pouch cells.\n                  <\/jats:p>","DOI":"10.1002\/adfm.79030","type":"journal-article","created":{"date-parts":[[2026,10,14]],"date-time":"2026-10-14T11:41:55Z","timestamp":1791978115000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Cross\u2010Phase Impurity\u2013Interphase Regulation for Suppressing Thermally Accelerated Failure in Ni\u2010Rich Pouch Lithium\u2010Ion Batteries"],"prefix":"10.1002","author":[{"given":"Xiang","family":"Gao","sequence":"first","affiliation":[{"name":"School of Chemistry South China Normal University  Guangzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yongqi","family":"Li","sequence":"additional","affiliation":[{"name":"School of Chemistry South China Normal University  Guangzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ruoke","family":"Li","sequence":"additional","affiliation":[{"name":"School of Chemistry South China Normal University  Guangzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiasheng","family":"Lu","sequence":"additional","affiliation":[{"name":"Guangzhou Tinci Materials Technology Co., Ltd.  Guangzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chaojun","family":"Fan","sequence":"additional","affiliation":[{"name":"Guangzhou Tinci Materials Technology Co., Ltd.  Guangzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Weizhen","family":"Fan","sequence":"additional","affiliation":[{"name":"Guangzhou Tinci Materials Technology Co., Ltd.  Guangzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaoyang","family":"Zhao","sequence":"additional","affiliation":[{"name":"School of Surveying and Environment Engineering Henan Polytechnic Institute  Nanyang China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Litao","family":"Shi","sequence":"additional","affiliation":[{"name":"Guangzhou Tinci Materials Technology Co., Ltd.  Guangzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6862-8978","authenticated-orcid":false,"given":"Junmin","family":"Nan","sequence":"additional","affiliation":[{"name":"School of Chemistry South China Normal University  Guangzhou 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