{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,16]],"date-time":"2026-10-16T03:44:36Z","timestamp":1792122276253,"version":"4.4.0"},"reference-count":39,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,10,15]],"date-time":"2026-10-15T00:00:00Z","timestamp":1792022400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,10,15]],"date-time":"2026-10-15T00:00:00Z","timestamp":1792022400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52202210"],"award-info":[{"award-number":["52202210"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100000923","name":"Australian Research Council","doi-asserted-by":"publisher","award":["LE0454166"],"award-info":[{"award-number":["LE0454166"]}],"id":[{"id":"10.13039\/501100000923","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Adv Funct Materials"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Lithium\u2010rich manganese\u2010based layered oxides can access both transition\u2010metal and oxygen redox, but activation of the monoclinic Li\n                    <jats:sub>2<\/jats:sub>\n                    MnO\n                    <jats:sub>3<\/jats:sub>\n                    component is usually sluggish and structurally unstable. Uncontrolled activation promotes irreversible lattice distortion, oxygen\u2010related degradation, voltage decay, and capacity loss. Here we use trace phosphorus substitution to regulate the activation pathway of a Li\u2010rich Mn\u2010based cathode. Structural, spectroscopic, microscopic, and theoretical analyses show that P tends to incorporate at Li\u2010layer sites near Ni\u2010containing local environments. This site\u2010selective substitution modifies the Li\u2010slab structure and adjacent Ni\u2500O\/O electronic environment, enabling more effective activation of the Li\u2010rich monoclinic component with a self\u2010relaxing lattice response. As a result, the P\u2010substituted cathode reaches a peak discharge capacity of 273.1 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at the 50th cycle and still delivers 270.5 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    after 300 cycles.\n                  <\/jats:p>","DOI":"10.1002\/adfm.79125","type":"journal-article","created":{"date-parts":[[2026,10,16]],"date-time":"2026-10-16T03:03:06Z","timestamp":1792119786000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Site\u2010Preferential Trace Phosphorus Substitution Accelerates and Stabilizes the Activation of Lithium\u2010Rich Cathode Materials"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-1253-6553","authenticated-orcid":false,"given":"Tongen","family":"Lin","sequence":"first","affiliation":[{"name":"School of Chemical Engineering and Australian Institute of Bioengineering and Nanotechnology The University of Queensland  Brisbane Queensland Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Gui","family":"Chu","sequence":"additional","affiliation":[{"name":"College of Materials Science and Engineering Changsha University of Science and Technology  Changsha China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8487-2620","authenticated-orcid":false,"given":"Xiaobo","family":"Zhu","sequence":"additional","affiliation":[{"name":"College of Materials Science and Engineering Changsha University of Science and Technology  Changsha China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shanshan","family":"Ding","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering and Australian Institute of Bioengineering and Nanotechnology The University of Queensland  Brisbane Queensland Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wei","family":"Chao","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering Monash University  Clayton Victoria Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3511-641X","authenticated-orcid":false,"given":"Mattia","family":"Colalongo","sequence":"additional","affiliation":[{"name":"ESRF\u2010The European Synchrotron  Grenoble France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4523-0841","authenticated-orcid":false,"given":"Tobias","family":"Schulli","sequence":"additional","affiliation":[{"name":"ESRF\u2010The European Synchrotron  Grenoble France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3199-3936","authenticated-orcid":false,"given":"Joanne","family":"Etheridge","sequence":"additional","affiliation":[{"name":"School of Physics and Astronomy Monash University  Clayton Victoria Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2088-6403","authenticated-orcid":false,"given":"Bin","family":"Luo","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering and Australian Institute of Bioengineering and Nanotechnology The University of Queensland  Brisbane Queensland Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5947-306X","authenticated-orcid":false,"given":"Lianzhou","family":"Wang","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering and Australian Institute of Bioengineering and Nanotechnology The University of Queensland  Brisbane Queensland Australia"},{"name":"Department of Applied Biology and Chemical Technology The Hong Kong Polytechnic University  Kowloon Hong Kong SAR China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,10,15]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.nanoen.2024.109620"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3CS00741C"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1039\/D5TA04248H"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.matt.2023.02.001"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6EE02328B"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1038\/nmat4551"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.0c00104"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560\u2010023\u201001289\u20106"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.9b02799"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.2524"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586\u2010021\u201003509\u2010z"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1038\/nmat3699"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/am503132t"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560\u2010021\u201000780\u20102"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41563\u2010024\u201001833\u2010z"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586\u2010022\u201004689\u2010y"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202521529"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560\u2010018\u20100207\u2010z"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1007\/s41918\u2010022\u201000172\u20104"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c01999"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202101962"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202213806"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202203045"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9TA00783K"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202518127"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2022.04.012"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3EE01318A"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5TA05657H"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1149\/1.1759292"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2009.09.029"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1149\/2.0361501jes"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c10485"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202212098"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2021.08.024"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja108588y"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201803392"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ces.2023.119526"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2023.233845"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201909192"}],"container-title":["Advanced Functional Materials"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/adfm.79125","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/adfm.79125","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/adfm.79125","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,10,16]],"date-time":"2026-10-16T03:03:10Z","timestamp":1792119790000},"score":1,"resource":{"primary":{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/10.1002\/adfm.79125"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,10,15]]},"references-count":39,"alternative-id":["10.1002\/adfm.79125"],"URL":"https:\/\/doi.org\/10.1002\/adfm.79125","archive":["Portico"],"relation":{},"ISSN":["1616-301X","1616-3028"],"issn-type":[{"value":"1616-301X","type":"print"},{"value":"1616-3028","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,10,15]]},"assertion":[{"value":"2026-07-13","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-10-12","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-10-15","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e79125"}}