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So far, numerous mussel\u2010inspired catechol\u2010based wet adhesives have been reported, opening a pathway for the treatment of acute trauma. However, catechol\u2010based hydrogels are easily oxidized, which limits their applications. Here, the design of a polyphosphazene and non\u2010catechol based antibacterial injectable hydrogel is reported as a multifunctional first aid bandage. Inspired by barnacle cement proteins, a series of dynamic phenylborate ester based adhesive hydrogels are prepared by combining the cation\u2013<jats:italic>\u03c0<\/jats:italic> structure modified polyphosphazene with polyvinyl alcohol. The inherent antibacterial property (4 h antibacterial rate 99.6 \u00b1 0.2%), anti\u2010mechanical damage, and hemostatic behavior are investigated to confirm multi\u2010functions of wound dressings. In water, the hydrogels firmly adhere to tissue surfaces through cation\u2013<jats:italic>\u03c0<\/jats:italic> and <jats:italic>\u03c0<\/jats:italic>\u2013<jats:italic>\u03c0<\/jats:italic> interactions as well as hydrogen bonding (adhesion strength = 45 kPa). Moreover, in vivo experiments indicate the hydrogels can shorten the bleeding time and reduce the amount of bleeding by 88%, and significantly accelerate the wound healing rate. These hydrogels have a promising application in the treatment of acute trauma, which is in urgent need of anti\u2010infection and hemostasis.<\/jats:p>","DOI":"10.1002\/adhm.202101421","type":"journal-article","created":{"date-parts":[[2021,10,27]],"date-time":"2021-10-27T04:18:28Z","timestamp":1635308308000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":89,"title":["Polyphosphazene and Non\u2010Catechol\u2010Based Antibacterial Injectable Hydrogel for Adhesion of Wet Tissues as Wound Dressing"],"prefix":"10.1002","volume":"11","author":[{"given":"Zhipeng","family":"Ni","sequence":"first","affiliation":[{"name":"State Key Laboratory of Chemical Engineering College of Chemical and Biological Engineering Zhejiang University  Hangzhou Zhejiang Province 310027 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