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These chronic implants require long\u2010term stability and small contact areas. Consequently, they are often coated with a blend of conductive polymers and are crosslinked to enhance durability despite the potentially deleterious effect of crosslinking on the mechanical and electrical properties. Here the grafting of the poly(3,4 ethylenedioxythiophene) scaffold, poly(styrenesulfonate)\u2010\n                    <jats:italic>b<\/jats:italic>\n                    \u2010poly(poly(ethylene glycol) methyl ether methacrylate block copolymer brush to gold, in a controlled and tunable manner, by surface\u2010initiated atom\u2010transfer radical polymerization (SI\u2010ATRP) is described. 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