{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,5,13]],"date-time":"2026-05-13T19:48:14Z","timestamp":1778701694862,"version":"3.51.4"},"reference-count":18,"publisher":"Wiley","issue":"11-12","license":[{"start":{"date-parts":[[2005,10,31]],"date-time":"2005-10-31T00:00:00Z","timestamp":1130716800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Annali di Chimica"],"published-print":{"date-parts":[[2005,11]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>In order to continue the investigation on the formation of hetero\u2010metal polynuclear hydrolytic species, in this paper we report some results (at <jats:italic>I<\/jats:italic> = 0.16 mol L<jats:sup>\u22121<\/jats:sup> in NaNO<jats:sub>3<\/jats:sub>, at t = 25 \u00b0C by potentiometry, ISE\u2010H<jats:sup>+<\/jats:sup>, glass electrode) on the hydrolysis of several mixtures (in different ratios) of the dioxouranium(VI) and cadmium(II) cations. The same experimental and calculation procedure of previously investigated systems was followed, and all measurements were performed by two different operators, using completely independent instruments and reagents. Many different speciation models were considered in the calculations, and a simple statistical analysis of obtained results was proposed too. UO<jats:sub>2<\/jats:sub><jats:sup>2+<\/jats:sup> and Cd<jats:sup>2+<\/jats:sup> form two heterometal polynuclear hydrolytic species, namely UO<jats:sub>2<\/jats:sub>Cd(OH)<jats:sup>3+<\/jats:sup> and (UO<jats:sub>2<\/jats:sub>)<jats:sub>2<\/jats:sub>Cd(OH)<jats:sub>4<\/jats:sub><jats:sup>2+<\/jats:sup>, with log\u03b2<jats:sub>pqr<\/jats:sub> = \u22123.25 \u00b1 0.25 and \u201013.75 \u00b1 0.10, respectively. The formation of heterometal hydrolytic species is thermodynamically favored with respect to the homo\u2010metal ones, and causes an enhancement of the percentage of hydrolyzed metal cations; comparisons with previously studied systems reveal that the hydrolytic behavior of UO<jats:sub>2<\/jats:sub><jats:sup>2+<\/jats:sup> \/ Cd<jats:sup>2+<\/jats:sup> mixtures is more similar to that observed for UO<jats:sub>2<\/jats:sub><jats:sup>2+<\/jats:sup> \/ Cu<jats:sup>2+<\/jats:sup> than for UO<jats:sub>2<\/jats:sub><jats:sup>2+<\/jats:sup> \/ (C<jats:sub>2<\/jats:sub>H<jats:sub>5<\/jats:sub>)<jats:sub>2<\/jats:sub>Sn<jats:sup>2+<\/jats:sup>, and the tendency to form hetero polynuclear hydrolytic species with dioxouranium(VI) by other cations follows the trend (C<jats:sub>2<\/jats:sub>H<jats:sub>5<\/jats:sub>)<jats:sub>2<\/jats:sub>Sn<jats:sup>2+<\/jats:sup> &gt; Cu<jats:sup>2+<\/jats:sup> \u2265 Cd<jats:sup>2+<\/jats:sup>.<\/jats:p>","DOI":"10.1002\/adic.200590090","type":"journal-article","created":{"date-parts":[[2005,10,31]],"date-time":"2005-10-31T12:19:49Z","timestamp":1130761189000},"page":"767-778","source":"Crossref","is-referenced-by-count":25,"title":["Enhancement of Hydrolysis through the Formation of Mixed Hetero\u2010Metal Species: Dioxouranium(VI) \u2013 Cadmium(II) Mixtures"],"prefix":"10.1002","volume":"95","author":[{"given":"Francesco","family":"Crea","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Demetrio","family":"Milea","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Silvio","family":"Sammartano","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2005,10,31]]},"reference":[{"key":"e_1_2_1_2_2","volume-title":"The Hydrolysis of Cations","author":"Baes C.F.","year":"1976"},{"key":"e_1_2_1_3_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.talanta.2004.06.014"},{"key":"e_1_2_1_4_2","first-page":"103","volume-title":"Mar. 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Motekaitis NIST Standard Reference Database 46 vers.8 Gaithersburg (2004)."},{"key":"e_1_2_1_18_2","volume-title":"Chemical Thermodynamics of Uranium","author":"Grenthe I.","year":"2004"},{"key":"e_1_2_1_19_2","doi-asserted-by":"publisher","DOI":"10.1021\/je000246j"}],"container-title":["Annali di Chimica"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fadic.200590090","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/adic.200590090","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,8,31]],"date-time":"2023-08-31T12:50:54Z","timestamp":1693486254000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/adic.200590090"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2005,10,31]]},"references-count":18,"journal-issue":{"issue":"11-12","published-print":{"date-parts":[[2005,11]]}},"alternative-id":["10.1002\/adic.200590090"],"URL":"https:\/\/doi.org\/10.1002\/adic.200590090","archive":["Portico"],"relation":{},"ISSN":["0003-4592","1612-8877"],"issn-type":[{"value":"0003-4592","type":"print"},{"value":"1612-8877","type":"electronic"}],"subject":[],"published":{"date-parts":[[2005,10,31]]}}}