{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2023,11,14]],"date-time":"2023-11-14T19:30:46Z","timestamp":1699990246619},"reference-count":28,"publisher":"Wiley","issue":"5-6","license":[{"start":{"date-parts":[[2006,6,21]],"date-time":"2006-06-21T00:00:00Z","timestamp":1150848000000},"content-version":"vor","delay-in-days":20,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Annali di Chimica"],"published-print":{"date-parts":[[2006,6]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Photodegradation of several thiols and thiones including 2\u2010pyrimidinethiol, thiazolidine\u20102\u2010thione, imidazolidine\u20102\u2010thione, 1,2,4\u2010triazole 3\u2010thiol and 2,5\u2010dimercapto\u20101,3,4\u2010thiadiazole have been studied in aerated aqueous solution using zinc oxide under irradiation with 400W high pressure mercury lamp. Rate constants span the range from 2.44\u00d710<jats:sup>\u20102<\/jats:sup> min.<jats:sup>\u20101<\/jats:sup> to 1.76\u00d710<jats:sup>\u20101<\/jats:sup> min.<jats:sup>\u20101<\/jats:sup>. The slower degradation rate of 2\u2010imidazoline2\u2010thione could be related to oxidation potential of the corresponding ring. The Langmuir\u2010Hinshelwood (L\u2010H) rate constant <jats:italic>k<jats:sub>r<\/jats:sub><\/jats:italic> and adsorption constant, (<jats:italic>K<\/jats:italic><jats:sub>A<\/jats:sub>) for all five thiols and thiones are reported.<\/jats:p>","DOI":"10.1002\/adic.200690029","type":"journal-article","created":{"date-parts":[[2006,6,21]],"date-time":"2006-06-21T11:20:17Z","timestamp":1150888817000},"page":"285-292","source":"Crossref","is-referenced-by-count":4,"title":["Photodegradation Kinetics of Some Thiols and Thiones in Aqueous Suspension of Zinc Oxide"],"prefix":"10.1002","volume":"96","author":[{"given":"Morteza","family":"Montazerozohori","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Bahador","family":"Karami","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Mohammad Hossein","family":"Habibi","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2006,6,21]]},"reference":[{"key":"e_1_2_1_2_2","volume-title":"ACS Symposium Series","author":"Zika R.G.","year":"1987"},{"key":"e_1_2_1_3_2","doi-asserted-by":"crossref","first-page":"358","DOI":"10.1021\/es00130a711","volume":"18","author":"Zafirion O.C.","year":"1984","journal-title":"Environ. 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