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After graphene and its counterparts, graphane, fluorographene, and others were introduced, waves of renewed interest in 2D binary compounds occurred, such as in metal oxides, transition\u2010metal dichalcogenides (most often represented by MoS<jats:sub>2<\/jats:sub>), metal oxy\/hydroxide borides, and MXenes, to name the most prominent. Recently, interest has turned to two\u2010dimensional monoelemental structures, such as monolayer black phosphorus and, very recently, to monolayer arsenic, antimony, and bismuth. Here, a short overview is provided of the area of exponentially increasing research in arsenene, antimonene, and bismuthene, which belong to the fifth main group of elements, the so\u2010called pnictogens. A short review of historical work is provided, the properties of bulk allotropes of As, Sb, and Bi discussed, and then theoretical and experimental research on mono\u2010 and few\u2010layered arsenene, antimonene, and bismuthene addressed, discussing their structures and properties.<\/jats:p>","DOI":"10.1002\/adma.201605299","type":"journal-article","created":{"date-parts":[[2017,2,10]],"date-time":"2017-02-10T02:35:12Z","timestamp":1486694112000},"source":"Crossref","is-referenced-by-count":733,"title":["2D Monoelemental Arsenene, Antimonene, and Bismuthene: Beyond Black Phosphorus"],"prefix":"10.1002","volume":"29","author":[{"given":"Martin","family":"Pumera","sequence":"first","affiliation":[{"name":"Division of Chemistry &amp; Biological Chemistry School of Physical and Mathematical Sciences Nanyang Technological University  Singapore 637371 Singapore"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zden\u011bk","family":"Sofer","sequence":"additional","affiliation":[{"name":"Department of Inorganic Chemistry University of Chemistry and Technology Prague  Technick\u00e1 5 166 28 Prague 6 Czech Republic"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2017,2,10]]},"reference":[{"key":"e_1_2_6_1_1","doi-asserted-by":"publisher","DOI":"10.1038\/natrevmats.2016.42"},{"key":"e_1_2_6_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/0039-6028(68)90089-7"},{"key":"e_1_2_6_3_1","first-page":"351","volume":"45","author":"Brodie B.","year":"1855","journal-title":"Ann. 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