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Due to their improved safety, polyanion framework compounds have recently gained attention as potential candidates. With the earth\u2010abundant element Fe being the redox center, the uniform carbon\u2010coated Na<jats:sub>3.32<\/jats:sub>Fe<jats:sub>2.34<\/jats:sub>(P<jats:sub>2<\/jats:sub>O<jats:sub>7<\/jats:sub>)<jats:sub>2<\/jats:sub>\/C composite represents a promising alternative for sodium\u2010ion batteries. The electrochemical results show that the as\u2010prepared Na<jats:sub>3.32<\/jats:sub>Fe<jats:sub>2.34<\/jats:sub>(P<jats:sub>2<\/jats:sub>O<jats:sub>7<\/jats:sub>)<jats:sub>2<\/jats:sub>\/C composite can deliver capacity of \u2248100 mA h g<jats:sup>\u22121<\/jats:sup> at 0.1 C (1 C = 120 mA g<jats:sup>\u22121<\/jats:sup>), with capacity retention of 92.3% at 0.5 C after 300 cycles. After adding fluoroethylene carbonate additive to the electrolyte, 89.6% of the initial capacity is maintained, even after 1100 cycles at 5 C. The electrochemical mechanism is systematically investigated via both in situ synchrotron X\u2010ray diffraction and density functional theory calculations. The results show that the sodiation and desodiation are single\u2010phase\u2010transition processes with two 1D sodium paths, which facilitates fast ionic diffusion. A small volume change, nearly 100% first\u2010cycle Coulombic efficiency, and a pseudocapacitance contribution are also demonstrated. This research indicates that this new compound could be a potential competitor for other iron\u2010based cathode electrodes for application in large\u2010scale Na rechargeable batteries.<\/jats:p>","DOI":"10.1002\/adma.201605535","type":"journal-article","created":{"date-parts":[[2017,3,29]],"date-time":"2017-03-29T07:45:25Z","timestamp":1490773525000},"source":"Crossref","is-referenced-by-count":223,"title":["Carbon\u2010Coated Na<sub>3.32<\/sub>Fe<sub>2.34<\/sub>(P<sub>2<\/sub>O<sub>7<\/sub>)<sub>2<\/sub> Cathode Material for High\u2010Rate and Long\u2010Life Sodium\u2010Ion Batteries"],"prefix":"10.1002","volume":"29","author":[{"given":"Mingzhe","family":"Chen","sequence":"first","affiliation":[{"name":"Institute for Superconducting and Electronic Materials Australian Institute for Innovative Materials University of Wollongong Innovation Campus  Squires Way North Wollongong NSW 2522 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