{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,27]],"date-time":"2026-10-27T19:37:02Z","timestamp":1793129822262,"version":"4.5.0"},"reference-count":46,"publisher":"Wiley","issue":"28","license":[{"start":{"date-parts":[[2017,5,31]],"date-time":"2017-05-31T00:00:00Z","timestamp":1496188800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21436010"],"award-info":[{"award-number":["21436010"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004731","name":"Natural Science Foundation of Zhejiang Province","doi-asserted-by":"publisher","award":["LR13B060001"],"award-info":[{"award-number":["LR13B060001"]}],"id":[{"id":"10.13039\/501100004731","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000928","name":"Welch Foundation","doi-asserted-by":"publisher","award":["AX\u20101730"],"award-info":[{"award-number":["AX\u20101730"]}],"id":[{"id":"10.13039\/100000928","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000928","name":"Welch Foundation","doi-asserted-by":"publisher","award":["1545669"],"award-info":[{"award-number":["1545669"]}],"id":[{"id":"10.13039\/100000928","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000928","name":"Welch Foundation","doi-asserted-by":"publisher","award":["1545670"],"award-info":[{"award-number":["1545670"]}],"id":[{"id":"10.13039\/100000928","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Advanced Materials"],"published-print":{"date-parts":[[2017,7]]},"abstract":"<jats:p>\n                    The efficient capture of SO\n                    <jats:sub>2<\/jats:sub>\n                    is of great significance in gas\u2010purification processes including flue\u2010gas desulfurization and natural\u2010gas purification, but the design of porous materials with high adsorption capacity and selectivity of SO\n                    <jats:sub>2<\/jats:sub>\n                    remains very challenging. Herein, the selective recognition and dense packing of SO\n                    <jats:sub>2<\/jats:sub>\n                    clusters through multiple synergistic host\u2013guest and guest\u2013guest interactions by controlling the pore chemistry and size in inorganic anion (SiF\n                    <jats:sub>6<\/jats:sub>\n                    <jats:sup>2\u2212<\/jats:sup>\n                    , SIFSIX) pillared metal\u2013organic frameworks is reported. The binding sites of anions and aromatic rings in SIFSIX materials grasp every atom of SO\n                    <jats:sub>2<\/jats:sub>\n                    firmly via S\n                    <jats:sup>\u03b4+<\/jats:sup>\n                    \u00b7\u00b7\u00b7F\n                    <jats:sup>\u03b4\u2212<\/jats:sup>\n                    electrostatic interactions and O\n                    <jats:sup>\u03b4\u2212<\/jats:sup>\n                    \u00b7\u00b7\u00b7H\n                    <jats:sup>\u03b4+<\/jats:sup>\n                    dipole\u2013dipole interactions, while the guest\u2013guest interactions between SO\n                    <jats:sub>2<\/jats:sub>\n                    molecules further promote gas trapping within the pore space, which is elucidated by first\u2010principles density functional theory calculations and powder X\u2010ray diffraction experiments. These interactions afford new benchmarks for the highly efficient removal of SO\n                    <jats:sub>2<\/jats:sub>\n                    from other gases, even if at a very low SO\n                    <jats:sub>2<\/jats:sub>\n                    concentration. Exceptionally high SO\n                    <jats:sub>2<\/jats:sub>\n                    capacity of 11.01 mmol g\n                    <jats:sup>\u22121<\/jats:sup>\n                    is achieved at atmosphere pressure by SIFSIX\u20101\u2010Cu, and unprecedented low\u2010pressure SO\n                    <jats:sub>2<\/jats:sub>\n                    capacity is obtained in SIFSIX\u20102\u2010Cu\u2010i (4.16 mmol g\n                    <jats:sup>\u22121<\/jats:sup>\n                    SO\n                    <jats:sub>2<\/jats:sub>\n                    at 0.01 bar and 2.31 mmol g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 0.002 bar). More importantly, record SO\n                    <jats:sub>2<\/jats:sub>\n                    \/CO\n                    <jats:sub>2<\/jats:sub>\n                    selectivity (86\u201389) and excellent SO\n                    <jats:sub>2<\/jats:sub>\n                    \/N\n                    <jats:sub>2<\/jats:sub>\n                    selectivity (1285\u20133145) are also achieved. Experimental breakthrough curves further demonstrate the excellent performance of these hybrid porous materials in removing low\u2010concentration SO\n                    <jats:sub>2<\/jats:sub>\n                    .\n                  <\/jats:p>","DOI":"10.1002\/adma.201606929","type":"journal-article","created":{"date-parts":[[2017,5,31]],"date-time":"2017-05-31T10:02:19Z","timestamp":1496224939000},"source":"Crossref","is-referenced-by-count":261,"title":["Ultrahigh and Selective SO\n                    <sub>2<\/sub>\n                    Uptake in Inorganic Anion\u2010Pillared Hybrid Porous Materials"],"prefix":"10.1002","volume":"29","author":[{"given":"Xili","family":"Cui","sequence":"first","affiliation":[{"name":"Key Laboratory of Biomass Chemical Engineering of Ministry of Education College of Chemical and Biological Engineering Zhejiang University  Hangzhou 310027 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qiwei","family":"Yang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Biomass Chemical Engineering of Ministry of Education College of Chemical and Biological Engineering Zhejiang University  Hangzhou 310027 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lifeng","family":"Yang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Biomass Chemical Engineering of Ministry of Education College of Chemical and Biological Engineering Zhejiang University  Hangzhou 310027 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rajamani","family":"Krishna","sequence":"additional","affiliation":[{"name":"Van' t Hoff Institute for Molecular Sciences University of Amsterdam  Science Park 904 Amsterdam 1098 XH The Netherlands"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhiguo","family":"Zhang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Biomass Chemical Engineering of Ministry of Education College of Chemical and Biological Engineering Zhejiang University  Hangzhou 310027 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zongbi","family":"Bao","sequence":"additional","affiliation":[{"name":"Key Laboratory of Biomass Chemical Engineering of Ministry of Education College of Chemical and Biological Engineering Zhejiang University  Hangzhou 310027 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hui","family":"Wu","sequence":"additional","affiliation":[{"name":"Center for Neutron Research National Institute of Standards and Technology  Gaithersburg MD 20899\u20106102 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qilong","family":"Ren","sequence":"additional","affiliation":[{"name":"Key Laboratory of Biomass Chemical Engineering of Ministry of Education College of Chemical and Biological Engineering Zhejiang University  Hangzhou 310027 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wei","family":"Zhou","sequence":"additional","affiliation":[{"name":"Center for Neutron Research National Institute of Standards and Technology  Gaithersburg MD 20899\u20106102 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8707-8115","authenticated-orcid":false,"given":"Banglin","family":"Chen","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Texas at San Antonio One UTSA Circle  San Antonio TX 78249\u20100698 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Huabin","family":"Xing","sequence":"additional","affiliation":[{"name":"Key Laboratory of Biomass Chemical Engineering of Ministry of Education College of Chemical and Biological Engineering Zhejiang 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