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Beyond these two approaches, a new unique, simple, yet ultrafast solid\u2010state explosive reaction is proposed to fabricate nanoporous bulk thermoelectric materials with well\u2010controlled pore sizes and distributions to suppress thermal conductivity. By investigating a wide variety of functional materials, general criteria for solid\u2010state explosive reactions are built upon both thermodynamics and kinetics, and then successfully used to tailor material's microstructures and porosity. A drastic decrease in lattice thermal conductivity down below the minimum value of the fully densified materials and enhancement in thermoelectric figure of merit are achieved in porous bulk materials. This work demonstrates that controlling materials' porosity is a very effective strategy and is easy to be combined with other approaches for optimizing thermoelectric performance.<\/jats:p>","DOI":"10.1002\/adma.201701148","type":"journal-article","created":{"date-parts":[[2017,9,29]],"date-time":"2017-09-29T13:06:41Z","timestamp":1506690401000},"source":"Crossref","is-referenced-by-count":160,"title":["Solid\u2010State Explosive Reaction for Nanoporous Bulk Thermoelectric Materials"],"prefix":"10.1002","volume":"29","author":[{"given":"Kunpeng","family":"Zhao","sequence":"first","affiliation":[{"name":"State Key Laboratory of High Performance Ceramics and Superfine Microstructure Shanghai Institute of Ceramics Chinese Academy of Sciences  Shanghai 200050 China"},{"name":"Shanghai Institute of Ceramics University of Chinese Academy of Sciences  Beijing 100049 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Haozhi","family":"Duan","sequence":"additional","affiliation":[{"name":"State Key Laboratory of High Performance Ceramics and Superfine Microstructure Shanghai Institute of Ceramics Chinese Academy of Sciences  Shanghai 200050 China"},{"name":"Shanghai Institute of Ceramics University of Chinese Academy of Sciences  Beijing 100049 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nunna","family":"Raghavendra","sequence":"additional","affiliation":[{"name":"State Key Laboratory of High Performance Ceramics and Superfine Microstructure Shanghai Institute of Ceramics Chinese Academy of Sciences  Shanghai 200050 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Pengfei","family":"Qiu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of High Performance Ceramics and Superfine Microstructure Shanghai Institute of Ceramics Chinese Academy of Sciences  Shanghai 200050 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yi","family":"Zeng","sequence":"additional","affiliation":[{"name":"State Key Laboratory of High Performance Ceramics and Superfine Microstructure Shanghai Institute of Ceramics Chinese Academy of Sciences  Shanghai 200050 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wenqing","family":"Zhang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of High Performance Ceramics and Superfine Microstructure Shanghai Institute of Ceramics Chinese Academy of Sciences  Shanghai 200050 China"},{"name":"Shanghai Institute of Materials Genome  Shanghai China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jihui","family":"Yang","sequence":"additional","affiliation":[{"name":"Materials Science and Engineering Department University of Washington  Seattle WA 98195 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xun","family":"Shi","sequence":"additional","affiliation":[{"name":"State Key Laboratory of High Performance Ceramics and Superfine Microstructure Shanghai Institute of Ceramics Chinese Academy of Sciences  Shanghai 200050 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lidong","family":"Chen","sequence":"additional","affiliation":[{"name":"State Key Laboratory of High Performance Ceramics and Superfine Microstructure Shanghai Institute of Ceramics Chinese Academy of Sciences  Shanghai 200050 China"},{"name":"Shanghai Institute of Materials Genome  Shanghai China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2017,9,29]]},"reference":[{"key":"e_1_2_5_1_1","doi-asserted-by":"publisher","DOI":"10.1039\/b822664b"},{"key":"e_1_2_5_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/nmat3273"},{"key":"e_1_2_5_3_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1158899"},{"key":"e_1_2_5_4_1","doi-asserted-by":"publisher","DOI":"10.1038\/nmat2090"},{"key":"e_1_2_5_5_1","first-page":"407","volume-title":"CRC Handbook of Thermoelectrics","author":"Slack G. 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