{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,16]],"date-time":"2026-10-16T23:22:57Z","timestamp":1792192977060,"version":"4.4.0"},"reference-count":21,"publisher":"Wiley","issue":"16","license":[{"start":{"date-parts":[[2020,3,4]],"date-time":"2020-03-04T00:00:00Z","timestamp":1583280000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Materials"],"published-print":{"date-parts":[[2020,4]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>A novel covalent, metal\u2010free, photocatalytic material is prepared by thermal polymerization of barbituric acid (BA). The structure of the photocatalyst is analyzed by using scanning electron microscopy, X\u2010ray diffraction, and infrared, UV\u2013visible, and <jats:sup>1<\/jats:sup>H solution and <jats:sup>13<\/jats:sup>C solid\u2010state NMR spectroscopy. The photodegradation efficiency of BA thermally polymerized at different temperatures is tested by photocatalytic degradation of aquatic rhodamine B (RhB) dye under visible\u2010light irradiation. It is shown that heating BA at an optimized temperature of 300 \u00b0C, that is, still in the range that polymer\u2010like polycondensation takes place, results in a photocatalyst that can remove RhB with 96% photodegradation efficiency after 70 min exposure to visible light. The polycondensation reaction of BA is identified to process through precipitation of trimer units as primary building blocks. Reference experiments such as addition of scavengers and saturation with oxygen are studied to understand the photodegradation process. It is shown that the presence of triethanolamine, and excess of oxygen and p\u2010benzoquinone in the solution of RhB and photocatalyst (BA300) is not beneficial, but decreases the photodegradation efficiency.<\/jats:p>","DOI":"10.1002\/adma.201907702","type":"journal-article","created":{"date-parts":[[2020,3,4]],"date-time":"2020-03-04T05:10:55Z","timestamp":1583298655000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":50,"title":["A New Conducting Polymer with Exceptional Visible\u2010Light Photocatalytic Activity Derived from Barbituric Acid Polycondensation"],"prefix":"10.1002","volume":"32","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-5140-5292","authenticated-orcid":false,"given":"Neda","family":"Keshavarzi","sequence":"first","affiliation":[{"name":"Max Planck Institute of Colloids and Interfaces Am M\u00fchlenberg 1  14476 Potsdam Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shaowen","family":"Cao","sequence":"additional","affiliation":[{"name":"State Key Lab of Advanced Technology Materials Synthesis &amp; Processing Wuhan University of Technology  Wuhan 430070 Hubei P. 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China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Markus","family":"Antonietti","sequence":"additional","affiliation":[{"name":"Max Planck Institute of Colloids and Interfaces Am M\u00fchlenberg 1  14476 Potsdam Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2020,3,4]]},"reference":[{"key":"e_1_2_6_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201501788"},{"key":"e_1_2_6_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201203732"},{"key":"e_1_2_6_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/cm503258z"},{"key":"e_1_2_6_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200903886"},{"key":"e_1_2_6_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/jhet.5570380318"},{"key":"e_1_2_6_6_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms11328"},{"key":"e_1_2_6_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.molliq.2016.12.090"},{"key":"e_1_2_6_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.seppur.2017.11.035"},{"key":"e_1_2_6_9_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9NJ01686D"},{"key":"e_1_2_6_10_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41598-017-04398-x"},{"key":"e_1_2_6_11_1","doi-asserted-by":"publisher","DOI":"10.1351\/pac198557040603"},{"key":"e_1_2_6_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201204453"},{"key":"e_1_2_6_13_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7GC02231J"},{"key":"e_1_2_6_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2017.08.055"},{"key":"e_1_2_6_15_1","doi-asserted-by":"publisher","DOI":"10.1039\/c1jm12620b"},{"key":"e_1_2_6_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/la404101h"},{"key":"e_1_2_6_17_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6RA04170A"},{"key":"e_1_2_6_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2017.06.017"},{"key":"e_1_2_6_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/la904023j"},{"key":"e_1_2_6_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/jz201242k"},{"key":"e_1_2_6_21_1","doi-asserted-by":"publisher","DOI":"10.1038\/nmat2317"}],"container-title":["Advanced Materials"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fadma.201907702","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/adma.201907702","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/adma.201907702","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/adma.201907702","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,6]],"date-time":"2025-10-06T16:39:19Z","timestamp":1759768759000},"score":1,"resource":{"primary":{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/10.1002\/adma.201907702"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2020,3,4]]},"references-count":21,"journal-issue":{"issue":"16","published-print":{"date-parts":[[2020,4]]}},"alternative-id":["10.1002\/adma.201907702"],"URL":"https:\/\/doi.org\/10.1002\/adma.201907702","archive":["Portico"],"relation":{},"ISSN":["0935-9648","1521-4095"],"issn-type":[{"value":"0935-9648","type":"print"},{"value":"1521-4095","type":"electronic"}],"subject":[],"published":{"date-parts":[[2020,3,4]]},"assertion":[{"value":"2019-11-23","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2020-03-04","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"1907702"}}