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Noble metal oxides possess promising capability for catalyzing water dissociation and hydrogen evolution; however, they are never utilized for the HER due to the instability under the reductive potential. Here it is shown that compressive strain can stabilize RhO<jats:sub>2<\/jats:sub> clusters and promote their catalytic activity. To this end, a strawberry\u2010like structure with RhO<jats:sub>2<\/jats:sub> clusters embedded in the surface layer of Rh nanoparticles is engineered, in which the incompatibility between the oxide cluster and the metal substrate causes intensive compressive strain. As such, RhO<jats:sub>2<\/jats:sub> clusters remain stable at a reduction potential up to \u22120.3 V versus reversible hydrogen electrode and present an alkaline HER activity superior to commercial Pt\/C.<\/jats:p>","DOI":"10.1002\/adma.201908521","type":"journal-article","created":{"date-parts":[[2020,5,18]],"date-time":"2020-05-18T01:27:04Z","timestamp":1589765224000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":149,"title":["Stable Rhodium (IV) Oxide for Alkaline Hydrogen Evolution Reaction"],"prefix":"10.1002","volume":"32","author":[{"given":"Zhe","family":"Li","sequence":"first","affiliation":[{"name":"Institute of New\u2010Energy Materials School of Materials Science and Engineering Key Laboratory for Advanced Ceramics and Machining Technology of Ministry of Education Tianjin University  Tianjin 300072 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