{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,11,7]],"date-time":"2026-11-07T17:24:07Z","timestamp":1794072247886,"version":"4.8.0"},"reference-count":32,"publisher":"Wiley","issue":"33","license":[{"start":{"date-parts":[[2021,7,6]],"date-time":"2021-07-06T00:00:00Z","timestamp":1625529600000},"content-version":"am","delay-in-days":365,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#am"},{"start":{"date-parts":[[2020,7,6]],"date-time":"2020-07-06T00:00:00Z","timestamp":1593993600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/100000015","name":"U.S. Department of Energy","doi-asserted-by":"publisher","award":["DE\u2010EE0008445"],"award-info":[{"award-number":["DE\u2010EE0008445"]}],"id":[{"id":"10.13039\/100000015","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Materials"],"published-print":{"date-parts":[[2020,8]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    High\u2010nickel LiNi\n                    <jats:sub>1\u2212<\/jats:sub>\n                    <jats:italic>\n                      <jats:sub>x<\/jats:sub>\n                    <\/jats:italic>\n                    <jats:sub>\u2212<\/jats:sub>\n                    <jats:italic>\n                      <jats:sub>y<\/jats:sub>\n                    <\/jats:italic>\n                    Mn\n                    <jats:italic>\n                      <jats:sub>x<\/jats:sub>\n                    <\/jats:italic>\n                    Co\n                    <jats:italic>\n                      <jats:sub>y<\/jats:sub>\n                    <\/jats:italic>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    (NMC) and LiNi\n                    <jats:sub>1\u2212<\/jats:sub>\n                    <jats:italic>\n                      <jats:sub>x<\/jats:sub>\n                    <\/jats:italic>\n                    <jats:sub>\u2212<\/jats:sub>\n                    <jats:italic>\n                      <jats:sub>y<\/jats:sub>\n                    <\/jats:italic>\n                    Co\n                    <jats:italic>\n                      <jats:sub>x<\/jats:sub>\n                    <\/jats:italic>\n                    Al\n                    <jats:italic>\n                      <jats:sub>y<\/jats:sub>\n                    <\/jats:italic>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    (NCA) are the cathode materials of choice for next\u2010generation high\u2010energy lithium\u2010ion batteries. Both NMC and NCA contain cobalt, an expensive and scarce metal generally believed to be essential for their electrochemical performance. Herein, a high\u2010Ni LiNi\n                    <jats:sub>1\u2212<\/jats:sub>\n                    <jats:italic>\n                      <jats:sub>x<\/jats:sub>\n                    <\/jats:italic>\n                    <jats:sub>\u2212<\/jats:sub>\n                    <jats:italic>\n                      <jats:sub>y<\/jats:sub>\n                    <\/jats:italic>\n                    Mn\n                    <jats:italic>\n                      <jats:sub>x<\/jats:sub>\n                    <\/jats:italic>\n                    Al\n                    <jats:italic>\n                      <jats:sub>y<\/jats:sub>\n                    <\/jats:italic>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    (NMA) cathode of desirable electrochemical properties is demonstrated benchmarked against NMC, NCA, and Al\u2013Mg\u2010codoped NMC (NMCAM) of identical Ni content (89 mol%) synthesized in\u2010house. Despite a slightly lower specific capacity, high\u2010Ni NMA operates at a higher voltage by \u224840\u00a0mV and shows no compromise in rate capability relative to NMC and NCA. In pouch cells paired with graphite, high\u2010Ni NMA outperforms both NMC and NCA and only slightly trails NMCAM and a commercial cathode after 1000 deep cycles. Further, the superior thermal stability of NMA to NMC, NCA, and NMCAM is shown using differential scanning calorimetry. Considering the flexibility in compositional tuning and immediate synthesis scalability of high\u2010Ni NMA very similar to NCA and NMC, this study opens a new space for cathode material development for next\u2010generation high\u2010energy, cobalt\u2010free Li\u2010ion batteries.\n                  <\/jats:p>","DOI":"10.1002\/adma.202002718","type":"journal-article","created":{"date-parts":[[2020,7,6]],"date-time":"2020-07-06T05:57:34Z","timestamp":1594015054000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":345,"title":["High\u2010Nickel NMA: A Cobalt\u2010Free Alternative to NMC and NCA Cathodes for Lithium\u2010Ion Batteries"],"prefix":"10.1002","volume":"32","author":[{"given":"Wangda","family":"Li","sequence":"first","affiliation":[{"name":"Science and Engineering Program and Texas Materials Institute The University of Texas at Austin  Austin TX 78712 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Steven","family":"Lee","sequence":"additional","affiliation":[{"name":"Science and Engineering Program and Texas Materials Institute The University of Texas at Austin  Austin TX 78712 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Arumugam","family":"Manthiram","sequence":"additional","affiliation":[{"name":"Science and Engineering Program and Texas Materials Institute The University of Texas at Austin  Austin TX 78712 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2020,7,6]]},"reference":[{"key":"e_1_2_5_1_1","doi-asserted-by":"publisher","DOI":"10.1016\/0025-5408(80)90012-4"},{"key":"e_1_2_5_2_1","doi-asserted-by":"publisher","DOI":"10.1246\/cl.2001.642"},{"key":"e_1_2_5_3_1","doi-asserted-by":"publisher","DOI":"10.1149\/1.1413182"},{"key":"e_1_2_5_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2003.10.009"},{"key":"e_1_2_5_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/cm901452z"},{"key":"e_1_2_5_6_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-020-15355-0"},{"key":"e_1_2_5_7_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-018-0107-2"},{"key":"e_1_2_5_8_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-019-0513-0"},{"key":"e_1_2_5_9_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aba9168"},{"key":"e_1_2_5_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0013-4686(99)00208-X"},{"key":"e_1_2_5_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201602888"},{"key":"e_1_2_5_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201702028"},{"key":"e_1_2_5_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201903179"},{"key":"e_1_2_5_14_1","doi-asserted-by":"publisher","DOI":"10.1149\/2.1381902jes"},{"key":"e_1_2_5_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.9b03515"},{"key":"e_1_2_5_16_1","doi-asserted-by":"publisher","DOI":"10.1149\/2.1101915jes"},{"key":"e_1_2_5_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.9b03603"},{"key":"e_1_2_5_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.0c00111"},{"key":"e_1_2_5_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/0167-2738(92)90164-K"},{"key":"e_1_2_5_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.8b03900"},{"key":"e_1_2_5_21_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2005.03.186"},{"key":"e_1_2_5_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201703154"},{"key":"e_1_2_5_23_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0378-7753(03)00145-9"},{"key":"e_1_2_5_24_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2005.03.083"},{"key":"e_1_2_5_25_1","doi-asserted-by":"publisher","DOI":"10.1149\/1.2943665"},{"key":"e_1_2_5_26_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ssi.2009.01.009"},{"key":"e_1_2_5_27_1","doi-asserted-by":"publisher","DOI":"10.1149\/2.0731811jes"},{"key":"e_1_2_5_28_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0378-7753(03)00175-7"},{"key":"e_1_2_5_29_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2014.02.018"},{"key":"e_1_2_5_30_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2014.02.103"},{"key":"e_1_2_5_31_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b13798"},{"key":"e_1_2_5_32_1","doi-asserted-by":"publisher","DOI":"10.1149\/2.0491913jes"}],"container-title":["Advanced Materials"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fadma.202002718","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/adma.202002718","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/adma.202002718","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/am-pdf\/10.1002\/adma.202002718","content-type":"application\/pdf","content-version":"am","intended-application":"syndication"},{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/adma.202002718","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,6]],"date-time":"2025-10-06T13:27:12Z","timestamp":1759757232000},"score":1,"resource":{"primary":{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/10.1002\/adma.202002718"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2020,7,6]]},"references-count":32,"journal-issue":{"issue":"33","published-print":{"date-parts":[[2020,8]]}},"alternative-id":["10.1002\/adma.202002718"],"URL":"https:\/\/doi.org\/10.1002\/adma.202002718","archive":["Portico"],"relation":{},"ISSN":["0935-9648","1521-4095"],"issn-type":[{"value":"0935-9648","type":"print"},{"value":"1521-4095","type":"electronic"}],"subject":[],"published":{"date-parts":[[2020,7,6]]},"assertion":[{"value":"2020-04-21","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2020-07-06","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"2002718"}}