{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,7]],"date-time":"2025-10-07T05:24:31Z","timestamp":1759814671222,"version":"build-2065373602"},"reference-count":45,"publisher":"Wiley","issue":"52","license":[{"start":{"date-parts":[[2020,11,16]],"date-time":"2020-11-16T00:00:00Z","timestamp":1605484800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003246","name":"Nederlandse Organisatie voor Wetenschappelijk Onderzoek","doi-asserted-by":"publisher","award":["016.Vidi.189.083"],"award-info":[{"award-number":["016.Vidi.189.083"]}],"id":[{"id":"10.13039\/501100003246","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Materials"],"published-print":{"date-parts":[[2020,12]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Forging customizable compounds into arbitrary shapes and structures has the potential to revolutionize functional materials, where independent control over shape and composition is essential. Current self\u2010assembly strategies allow impressive levels of control over either shape or composition, but not both, as self\u2010assembly inherently entangles shape and composition. Herein, independent control over shape and composition is achieved by chemical conversion reactions on nanocrystals, which are first self\u2010assembled in nanocomposites with programmable microscopic shapes. The multiscale character of nanocomposites is crucial: nanocrystals (5\u201350\u00a0nm) offer enhanced chemical reactivity, while the composite layout accommodates volume changes of the nanocrystals (<jats:bold>\u2248<\/jats:bold>25%), which together leads to complete chemical conversion with full shape preservation. These reactions are surprisingly materials agnostic, allowing a large diversity of chemical pathways, and development of conversion pathways yielding a wide selection of shape\u2010controlled transition metal chalcogenides (cadmium, manganese, iron, and nickel oxides and sulfides). Finally, the versatility and application potential of this strategy is demonstrated by assembling: 1) a scalable and highly reactive nickel catalyst for the dry reforming of butane, 2) an agile magnetic\u2010controlled particle, and 3) an electron\u2010beam\u2010controlled reversible microactuator with sub\u2010micrometer precision. Previously unimaginable customization of shape and composition is now achievable for assembling advanced functional components.<\/jats:p>","DOI":"10.1002\/adma.202003999","type":"journal-article","created":{"date-parts":[[2020,11,16]],"date-time":"2020-11-16T03:54:02Z","timestamp":1605498842000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":25,"title":["Shape\u2010Preserving Chemical Conversion of Architected Nanocomposites"],"prefix":"10.1002","volume":"32","author":[{"given":"Hans C.","family":"Hendrikse","sequence":"first","affiliation":[{"name":"AMOLF  Science Park 104 Amsterdam 1098 XG The Netherlands"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Arno","family":"van der Weijden","sequence":"additional","affiliation":[{"name":"AMOLF  Science Park 104 Amsterdam 1098 XG The Netherlands"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Maria","family":"Ronda\u2010Lloret","sequence":"additional","affiliation":[{"name":"Van \u2018t Hoff Institute for Molecular Sciences University of Amsterdam  Science Park 904 Amsterdam 1090 GD The Netherlands"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ting","family":"Yang","sequence":"additional","affiliation":[{"name":"Department of Mechanical Engineering Virginia Polytechnic Institute and State University  Blacksburg VA 24060 USA"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Roland","family":"Bliem","sequence":"additional","affiliation":[{"name":"ARCNL  Science Park 106 Amsterdam 1098 XG The Netherlands"},{"name":"Institute of Physics University of Amsterdam  Science Park 904 Amsterdam 1098 XH The Netherlands"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"N. Raveendran","family":"Shiju","sequence":"additional","affiliation":[{"name":"Van \u2018t Hoff Institute for Molecular Sciences University of Amsterdam  Science Park 904 Amsterdam 1090 GD The Netherlands"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Martin","family":"van Hecke","sequence":"additional","affiliation":[{"name":"AMOLF  Science Park 104 Amsterdam 1098 XG The Netherlands"},{"name":"Leiden Institute of Physics Leiden University  Niels Bohrweg 2 Leiden 2333 CA The Netherlands"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ling","family":"Li","sequence":"additional","affiliation":[{"name":"Department of Mechanical Engineering Virginia Polytechnic Institute and State University  Blacksburg VA 24060 USA"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0028-2354","authenticated-orcid":false,"given":"Willem L.","family":"Noorduin","sequence":"additional","affiliation":[{"name":"AMOLF  Science Park 104 Amsterdam 1098 XG The Netherlands"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2020,11,16]]},"reference":[{"key":"e_1_2_5_1_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aat8297"},{"key":"e_1_2_5_2_1","doi-asserted-by":"publisher","DOI":"10.1557\/mrs.2016.168"},{"key":"e_1_2_5_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr8002856"},{"key":"e_1_2_5_4_1","doi-asserted-by":"publisher","DOI":"10.1093\/oso\/9780195049770.001.0001"},{"key":"e_1_2_5_5_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aav4299"},{"key":"e_1_2_5_6_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms13912"},{"key":"e_1_2_5_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/ijch.201700136"},{"key":"e_1_2_5_8_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1165349"},{"key":"e_1_2_5_9_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1234621"},{"key":"e_1_2_5_10_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aah6350"},{"key":"e_1_2_5_11_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1070821"},{"key":"e_1_2_5_12_1","doi-asserted-by":"publisher","DOI":"10.1038\/nature05570"},{"key":"e_1_2_5_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201201471"},{"key":"e_1_2_5_14_1","doi-asserted-by":"publisher","DOI":"10.1038\/nmat4089"},{"key":"e_1_2_5_15_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6CS00432F"},{"key":"e_1_2_5_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr400081d"},{"key":"e_1_2_5_17_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-019-1538-z"},{"key":"e_1_2_5_18_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41563-019-0404-6"},{"key":"e_1_2_5_19_1","doi-asserted-by":"publisher","DOI":"10.1038\/nature04414"},{"key":"e_1_2_5_20_1","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.2303"},{"key":"e_1_2_5_21_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aad0371"},{"key":"e_1_2_5_22_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1254132"},{"key":"e_1_2_5_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp405989z"},{"key":"e_1_2_5_24_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1252642"},{"key":"e_1_2_5_25_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1250884"},{"key":"e_1_2_5_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b10624"},{"key":"e_1_2_5_27_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1174401"},{"key":"e_1_2_5_28_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41557-018-0064-1"},{"key":"e_1_2_5_29_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5NH00094G"},{"key":"e_1_2_5_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201908218"},{"key":"e_1_2_5_31_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-018-07658-0"},{"volume-title":"High Temperature Properties and Thermal Composition of Inorganic Salts","year":"2001","author":"Stern K. H.","key":"e_1_2_5_32_1"},{"key":"e_1_2_5_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/cm403812y"},{"key":"e_1_2_5_34_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2cs35310e"},{"volume-title":"Iron Oxides: From Nature to Applications","year":"2016","author":"Hirt A. M.","key":"e_1_2_5_35_1"},{"key":"e_1_2_5_36_1","doi-asserted-by":"publisher","DOI":"10.1111\/j.1151-2916.1956.tb15639.x"},{"key":"e_1_2_5_37_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1195875"},{"key":"e_1_2_5_38_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr500486u"},{"key":"e_1_2_5_39_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7CY01067B"},{"key":"e_1_2_5_40_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.6b02176"},{"key":"e_1_2_5_41_1","doi-asserted-by":"publisher","DOI":"10.1007\/s13399-019-00417-1"},{"key":"e_1_2_5_42_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.fuproc.2017.10.007"},{"key":"e_1_2_5_43_1","doi-asserted-by":"crossref","first-page":"541","DOI":"10.1063\/1.1654741","volume":"23","author":"Sigsbee R. A.","year":"1973","journal-title":"Appl. Phys. Lett."},{"key":"e_1_2_5_44_1","doi-asserted-by":"publisher","DOI":"10.1016\/B978-0-08-057103-4.50013-1"},{"key":"e_1_2_5_45_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201902047"}],"container-title":["Advanced Materials"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/adma.202003999","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/adma.202003999","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/adma.202003999","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,6]],"date-time":"2025-10-06T11:11:32Z","timestamp":1759749092000},"score":1,"resource":{"primary":{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/10.1002\/adma.202003999"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2020,11,16]]},"references-count":45,"journal-issue":{"issue":"52","published-print":{"date-parts":[[2020,12]]}},"alternative-id":["10.1002\/adma.202003999"],"URL":"https:\/\/doi.org\/10.1002\/adma.202003999","archive":["Portico"],"relation":{},"ISSN":["0935-9648","1521-4095"],"issn-type":[{"type":"print","value":"0935-9648"},{"type":"electronic","value":"1521-4095"}],"subject":[],"published":{"date-parts":[[2020,11,16]]},"assertion":[{"value":"2020-06-11","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2020-11-16","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"2003999"}}