{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,8]],"date-time":"2026-04-08T21:22:07Z","timestamp":1775683327403,"version":"3.50.1"},"reference-count":29,"publisher":"Wiley","issue":"16","license":[{"start":{"date-parts":[[2022,3,10]],"date-time":"2022-03-10T00:00:00Z","timestamp":1646870400000},"content-version":"am","delay-in-days":365,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#am"},{"start":{"date-parts":[[2021,3,10]],"date-time":"2021-03-10T00:00:00Z","timestamp":1615334400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100009025","name":"Accelerated Innovation Research Initiative Turning Top Science and Ideas into High-Impact Values","doi-asserted-by":"publisher","award":["JPMJAC1501"],"award-info":[{"award-number":["JPMJAC1501"]}],"id":[{"id":"10.13039\/501100009025","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Materials"],"published-print":{"date-parts":[[2021,4]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Since 1970, people have been making every endeavor to reduce toxic emissions from automobiles. After the development of a three\u2010way catalyst (TWC) that concurrently converts three harmful gases, carbon monoxide (CO), hydrocarbons (HCs), and nitrogen oxides (NO<jats:italic><jats:sub>x<\/jats:sub><\/jats:italic>), Rh became an essential element in automobile technology because only Rh works efficiently for catalytic NO<jats:italic><jats:sub>x<\/jats:sub><\/jats:italic> reduction. However, due to the sharp price spike in 2007, numerous efforts have been made to replace Rh in TWCs. Nevertheless, Rh remains irreplaceable, and now, the price of Rh is increasing significantly again. Here, it is demonstrated that PdRuM ternary solid\u2010solution alloy nanoparticles (NPs) exhibit highly durable and active TWC performance, which will result in a significant reduction in catalyst cost compared to Rh. This work provides insights into the design of highly durable and efficient functional alloy NPs, guiding how to best take advantage of the configurational entropy in addition to the mixing enthalpy.<\/jats:p>","DOI":"10.1002\/adma.202005206","type":"journal-article","created":{"date-parts":[[2021,3,10]],"date-time":"2021-03-10T03:05:28Z","timestamp":1615345528000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":43,"title":["Highly Stable and Active Solid\u2010Solution\u2010Alloy Three\u2010Way Catalyst by Utilizing Configurational\u2010Entropy Effect"],"prefix":"10.1002","volume":"33","author":[{"given":"Kohei","family":"Kusada","sequence":"first","affiliation":[{"name":"Division of Chemistry Graduate School of Science Kyoto University  Kitashirakawa\u2010Oiwakecho, Sakyo\u2010ku Kyoto 606\u20108502 Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Dongshuang","family":"Wu","sequence":"additional","affiliation":[{"name":"Division of Chemistry Graduate School of Science Kyoto University  Kitashirakawa\u2010Oiwakecho, Sakyo\u2010ku Kyoto 606\u20108502 Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yusuke","family":"Nanba","sequence":"additional","affiliation":[{"name":"Center for Green Research on Energy and Environmental Materials National Institute for Materials Science  1\u20101 Namiki Tsukuba Ibaraki 305\u20100044 Japan"},{"name":"Research Initiative for Supra\u2010Materials Shinshu University  4\u201017\u20101 Wakasato Nagano 380\u20108553 Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Michihisa","family":"Koyama","sequence":"additional","affiliation":[{"name":"Center for Green Research on Energy and Environmental Materials National Institute for Materials Science  1\u20101 Namiki Tsukuba Ibaraki 305\u20100044 Japan"},{"name":"Research Initiative for Supra\u2010Materials Shinshu University  4\u201017\u20101 Wakasato Nagano 380\u20108553 Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Tomokazu","family":"Yamamoto","sequence":"additional","affiliation":[{"name":"Department of Applied Quantum Physics and Nuclear Engineering Kyushu University  744 Motooka, Nishi\u2010ku Fukuoka 819\u20100395 Japan"},{"name":"The Ultramicroscopy Research Center Kyushu University  744 Motooka, Nishi\u2010ku Fukuoka 819\u20100395 Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Xuan Quy","family":"Tran","sequence":"additional","affiliation":[{"name":"Department of Applied Quantum Physics and Nuclear Engineering Kyushu University  744 Motooka, Nishi\u2010ku Fukuoka 819\u20100395 Japan"},{"name":"The Ultramicroscopy Research Center Kyushu University  744 Motooka, Nishi\u2010ku Fukuoka 819\u20100395 Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Takaaki","family":"Toriyama","sequence":"additional","affiliation":[{"name":"Department of Applied Quantum Physics and Nuclear Engineering Kyushu University  744 Motooka, Nishi\u2010ku Fukuoka 819\u20100395 Japan"},{"name":"The Ultramicroscopy Research Center Kyushu University  744 Motooka, Nishi\u2010ku Fukuoka 819\u20100395 Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Syo","family":"Matsumura","sequence":"additional","affiliation":[{"name":"Department of Applied Quantum Physics and Nuclear Engineering Kyushu University  744 Motooka, Nishi\u2010ku Fukuoka 819\u20100395 Japan"},{"name":"The Ultramicroscopy Research Center Kyushu University  744 Motooka, Nishi\u2010ku Fukuoka 819\u20100395 Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ayano","family":"Ito","sequence":"additional","affiliation":[{"name":"Department of Integrated Science and Technology Faculty of Science and Technology Oita University  700 Dannoharu Oita 870\u20101192 Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Katsutoshi","family":"Sato","sequence":"additional","affiliation":[{"name":"Elements Strategy Initiative for Catalysts and Batteries Kyoto University  1\u201030 Goryo\u2010Ohara, Nishikyo\u2010ku Kyoto 615\u20108245 Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Katsutoshi","family":"Nagaoka","sequence":"additional","affiliation":[{"name":"Department of Chemical Systems Engineering Graduate School of Engineering Nagoya University  Furo\u2010cho, Chikusa\u2010ku Nagoya 464\u20108601 Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Okkyun","family":"Seo","sequence":"additional","affiliation":[{"name":"Synchrotron X\u2010ray Group and Synchrotron X\u2010ray Station at SPring\u20108 National Institute for Materials Science  Kouto, Sayo\u2010cho, Sayo\u2010gun Hyogo 679\u20105148 Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Chulho","family":"Song","sequence":"additional","affiliation":[{"name":"Synchrotron X\u2010ray Group and Synchrotron X\u2010ray Station at SPring\u20108 National Institute for Materials Science  Kouto, Sayo\u2010cho, Sayo\u2010gun Hyogo 679\u20105148 Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yanna","family":"Chen","sequence":"additional","affiliation":[{"name":"Synchrotron X\u2010ray Group and Synchrotron X\u2010ray Station at SPring\u20108 National Institute for Materials Science  Kouto, Sayo\u2010cho, Sayo\u2010gun Hyogo 679\u20105148 Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Natalia","family":"Palina","sequence":"additional","affiliation":[{"name":"Synchrotron X\u2010ray Group and Synchrotron X\u2010ray Station at SPring\u20108 National Institute for Materials Science  Kouto, Sayo\u2010cho, Sayo\u2010gun Hyogo 679\u20105148 Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Loku Singgappulige Rosantha","family":"Kumara","sequence":"additional","affiliation":[{"name":"Synchrotron X\u2010ray Group and Synchrotron X\u2010ray Station at SPring\u20108 National Institute for Materials Science  Kouto, Sayo\u2010cho, Sayo\u2010gun Hyogo 679\u20105148 Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Satoshi","family":"Hiroi","sequence":"additional","affiliation":[{"name":"Synchrotron X\u2010ray Group and Synchrotron X\u2010ray Station at SPring\u20108 National Institute for Materials Science  Kouto, Sayo\u2010cho, Sayo\u2010gun Hyogo 679\u20105148 Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Osami","family":"Sakata","sequence":"additional","affiliation":[{"name":"Synchrotron X\u2010ray Group and Synchrotron X\u2010ray Station at SPring\u20108 National Institute for Materials Science  Kouto, Sayo\u2010cho, Sayo\u2010gun Hyogo 679\u20105148 Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Shogo","family":"Kawaguchi","sequence":"additional","affiliation":[{"name":"Japan Synchrotron Radiation Research Institute (JASRI) SPring\u20108  1\u20101\u20101 Kouto, Sayo\u2010cho, Sayo\u2010gun Hyogo 679\u20105198 Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yoshiki","family":"Kubota","sequence":"additional","affiliation":[{"name":"Department of Physical Science Graduate School of Science Osaka Prefecture University  1\u20101 Gakuen\u2010cho, Naka\u2010ku, Sakai Osaka 599\u20108531 Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6955-3015","authenticated-orcid":false,"given":"Hiroshi","family":"Kitagawa","sequence":"additional","affiliation":[{"name":"Division of Chemistry Graduate School of Science Kyoto University  Kitashirakawa\u2010Oiwakecho, Sakyo\u2010ku Kyoto 606\u20108502 Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2021,3,10]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-019-0312-9"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1039\/b719206c"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja107362z"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201800650"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-018-02933-6"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8SC04135K"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201502881"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201903928"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja409464g"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1038\/srep28265"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/adem.200300567"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.msea.2003.10.257"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1080\/21663831.2014.912690"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms8748"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja300708j"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp203457f"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.4999454"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1007\/BF02881271"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1007\/BF02880404"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.0c06813"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/nl302405k"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpclett.5b02753"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1595\/147106707X205857"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.54.11169"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1016\/0927-0256(96)00008-0"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.77.3865"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.50.17953"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.59.1758"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1107\/S0021889871006174"}],"container-title":["Advanced Materials"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/adma.202005206","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/adma.202005206","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/am-pdf\/10.1002\/adma.202005206","content-type":"application\/pdf","content-version":"am","intended-application":"syndication"},{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/adma.202005206","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,6]],"date-time":"2025-10-06T10:22:32Z","timestamp":1759746152000},"score":1,"resource":{"primary":{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/10.1002\/adma.202005206"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2021,3,10]]},"references-count":29,"journal-issue":{"issue":"16","published-print":{"date-parts":[[2021,4]]}},"alternative-id":["10.1002\/adma.202005206"],"URL":"https:\/\/doi.org\/10.1002\/adma.202005206","archive":["Portico"],"relation":{},"ISSN":["0935-9648","1521-4095"],"issn-type":[{"value":"0935-9648","type":"print"},{"value":"1521-4095","type":"electronic"}],"subject":[],"published":{"date-parts":[[2021,3,10]]},"assertion":[{"value":"2020-07-31","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2021-03-10","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"2005206"}}