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Among them, black phosphorus (BP) is one of the most promising materials on account of its thickness\u2010dependent bandgap, high charge\u2010carrier mobility, in\u2010plane anisotropic structure, and excellent biocompatibility, as well as the broad applications brought by the properties. In view of the electron configuration, the most unique feature of BP is the lone\u2010pair electrons on each P atom. The lone\u2010pair electrons inevitably cause high reactivity of BP, particularly toward water\/oxygen, which greatly limits the practical application of BP under ambient conditions. The other side of the coin is that BP can serve as an electron donor to promote the construction of BP\u2010based hybrid materials and\/or to boost the performance of BP or BP\u2010based hybrid materials in applications. Here, recent advances in passivation and application of BP by addressing the interaction between the lone\u2010pair electrons of BP and the other materials are discussed, and prospects for future research on BP are also proposed.<\/jats:p>","DOI":"10.1002\/adma.202005924","type":"journal-article","created":{"date-parts":[[2021,5,29]],"date-time":"2021-05-29T07:44:12Z","timestamp":1622274252000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":55,"title":["Electron Matters: Recent Advances in Passivation and Applications of Black Phosphorus"],"prefix":"10.1002","volume":"33","author":[{"given":"Xiao","family":"Liu","sequence":"first","affiliation":[{"name":"Department of Physics Research Institute for Biomimetics and Soft Matter Fujian Provincial Key Laboratory for Soft Functional Materials Xiamen University  Xiamen 361005 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