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Nevertheless, their actual implementation is still far from a reality since the trade\u2010off relationship between the particle size and chemical reversibility prevents LMRs from achieving a satisfactory, industrial energy density. To solve this material dilemma, herein, a novel morphological and structural design is introduced to Li<jats:sub>1.11<\/jats:sub>Mn<jats:sub>0.49<\/jats:sub>Ni<jats:sub>0.29<\/jats:sub>Co<jats:sub>0.11<\/jats:sub>O<jats:sub>2<\/jats:sub>, reporting a sub\u2010micrometer\u2010level LMR with a relatively delocalized, excess\u2010Li system. This system exhibits an ultrahigh energy density of 2880\u00a0Wh L<jats:sup>\u22121<\/jats:sup> and a long\u2010lasting cycle retention of 83.1% after the 100th cycle for 45 \u00b0C full\u2010cell cycling, despite its practical electrode conditions. This outstanding electrochemical performance is a result of greater lattice\u2010oxygen stability in the delocalized excess\u2010Li system because of the low amount of highly oxidized oxygen ions. Geometric dispersion of the labile oxygen ions effectively suppresses oxygen evolution from the lattice when delithiated, eradicating the rapid energy degradation in a practical cell system.<\/jats:p>","DOI":"10.1002\/adma.202100352","type":"journal-article","created":{"date-parts":[[2021,3,30]],"date-time":"2021-03-30T01:42:24Z","timestamp":1617068544000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":55,"title":["Lattice\u2010Oxygen\u2010Stabilized Li\u2010 and Mn\u2010Rich Cathodes with Sub\u2010Micrometer Particles by Modifying the Excess\u2010Li Distribution"],"prefix":"10.1002","volume":"33","author":[{"given":"Jaeseong","family":"Hwang","sequence":"first","affiliation":[{"name":"Department of Energy Engineering Department of Energy and Chemical Engineering Ulsan National Institute of Science and Technology (UNIST)  50 UNIST\u2010gil Ulsan 44919 Republic of 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