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Nevertheless, their efficiencies remain unsatisfactory due to insufficient film quality on hydrophobic hole transport layer and limited hole\u2010blocking capability of the electron transport layer. Herein, 1,3,5\u2010Tris(1\u2010phenyl\u20101H\u2010benzimidazol\u20102\u2010yl)benzene (TPBi), an n\u2010type semiconductor, is incorporated into the antisolvent to simultaneously regulate the grain growth and charge transport of perovskite films. TPBi facilitates the crystallization of perovskites along (100) orientation. Besides, TPBi is mainly distributed near the top surface of perovskite film and enhances the hole\u2010blocking capability of the area adjacent to the surface. The superior properties of this film lead to a remarkable improvement in the open\u2010circuit voltage of inverted PSCs. The champion device achieves a high power conversion efficiency of 21.79% while keeping \u224892% of its initial value after 1000 h storage in the ambient atmosphere. This work provides an effective way to evidently promote the performance of inverted PSCs and illustrates its underlaying mechanism.<\/jats:p>","DOI":"10.1002\/adma.202102816","type":"journal-article","created":{"date-parts":[[2021,8,2]],"date-time":"2021-08-02T07:48:07Z","timestamp":1627890487000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":109,"title":["Antisolvent Engineering to Optimize Grain Crystallinity and Hole\u2010Blocking Capability of Perovskite Films for High\u2010Performance Photovoltaics"],"prefix":"10.1002","volume":"33","author":[{"given":"Yulan","family":"Huang","sequence":"first","affiliation":[{"name":"Joint Key Laboratory of the Ministry of Education Institute of Applied Physics and Materials Engineering University of Macau Avenida da Universidade  Taipa Macau 999078 China"},{"name":"Department of Materials Science and Engineering Southern University of Science and Technology  Shenzhen Guangdong Province 518055 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tanghao","family":"Liu","sequence":"additional","affiliation":[{"name":"Joint Key Laboratory of the Ministry of Education Institute of Applied Physics and Materials Engineering University of Macau Avenida da Universidade  Taipa Macau 999078 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bingzhe","family":"Wang","sequence":"additional","affiliation":[{"name":"Joint Key Laboratory of the Ministry of Education Institute of Applied Physics and Materials Engineering University of Macau Avenida da Universidade  Taipa Macau 999078 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jielei","family":"Li","sequence":"additional","affiliation":[{"name":"Joint Key Laboratory of the Ministry of Education Institute of Applied Physics and Materials Engineering University of Macau Avenida da Universidade  Taipa Macau 999078 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dongyang","family":"Li","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering Southern University of Science and Technology  Shenzhen Guangdong Province 518055 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guoliang","family":"Wang","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering Southern University of Science and Technology  Shenzhen Guangdong Province 518055 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qing","family":"Lian","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering Southern University of Science and Technology  Shenzhen Guangdong Province 518055 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Abbas","family":"Amini","sequence":"additional","affiliation":[{"name":"Center for Infrastructure Engineering Western Sydney University  Kingswood NSW 2751 Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shi","family":"Chen","sequence":"additional","affiliation":[{"name":"Joint Key Laboratory of the Ministry of Education Institute of Applied Physics and Materials Engineering University of Macau Avenida da Universidade  Taipa Macau 999078 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chun","family":"Cheng","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering Southern University of Science and Technology  Shenzhen Guangdong Province 518055 China"},{"name":"Guangdong Provincial Key Laboratory of Energy Materials for Electric Power Southern University of Science and Technology  Shenzhen Guangdong Province 518055 China"},{"name":"Shenzhen Engineering Research and Development Center for Flexible Solar Cells Southern University of Science and Technology  Shenzhen Guangdong Province 518055 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4507-2812","authenticated-orcid":false,"given":"Guichuan","family":"Xing","sequence":"additional","affiliation":[{"name":"Joint Key Laboratory of the Ministry of Education Institute of Applied Physics and Materials Engineering University of Macau Avenida da Universidade  Taipa Macau 999078 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2021,8,2]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-019-1357-2"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.0c00107"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41566-019-0398-2"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja809598r"},{"key":"e_1_2_8_5_1","unstructured":"Research Cell Effciency Records. 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