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However, severe shuttling effect caused by the dissolution of active materials in liquid electrolytes results in fast capacity decay, limiting their practical applications. Here, using a gel polymer electrolyte (GPE) that is in situ formed on Nafion\u2010coated separators, the shuttle reaction of organic electrodes is eliminated while maintaining the electrochemical performance. The synergy of physical confinement by GPE with tunable polymer structure and charge repulsion of the Nafion\u2010coated separator substantially prevents the soluble organic electrode materials with different molecular sizes from shuttling. A soluble small\u2010molecule organic electrode material of 1,3,5\u2010tri(9,10\u2010anthraquinonyl)benzene demonstrates exceptional electrochemical performance with an ultra\u2010long cycle life of 10\u202f000 cycles, excellent rate capability of 203 mAh g<jats:sup>\u22121<\/jats:sup> at 100 C, and a wide working temperature range from \u221270 to 100\u00a0\u00b0C based on the solid\u2013liquid conversion chemistry, which outperforms all previously reported organic cathode materials. The shielding capability of GPE can be designed and tailored toward organic electrodes with different molecular sizes, thus providing a universal resolution to the shuttling effect that all soluble electrode materials suffer.<\/jats:p>","DOI":"10.1002\/adma.202107226","type":"journal-article","created":{"date-parts":[[2021,11,19]],"date-time":"2021-11-19T00:39:02Z","timestamp":1637282342000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":100,"title":["Soluble Organic Cathodes Enable Long Cycle Life, High Rate, and Wide\u2010Temperature Lithium\u2010Ion Batteries"],"prefix":"10.1002","volume":"34","author":[{"given":"Mengjie","family":"Li","sequence":"first","affiliation":[{"name":"School of Materials Science and Engineering Key Laboratory of Advanced Ceramics and Machining Technology (Ministry of Education), and Tianjin Key Laboratory of Composite and Functional Materials Tianjin University  Tianjin 300072 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