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However, the utility of such c\u2010MOFs in high\u2010performance devices has been limited to date by the lack of high\u2010quality MOF thin\u2010film processing. Herein, a technique known as the microfluidic\u2010assisted solution shearing combined with post\u2010synthetic rapid crystallization (MASS\u2010PRC) process is introduced to generate a high\u2010quality, flexible, and transparent thin\u2010film of Ni<jats:sub>3<\/jats:sub>(hexaiminotriphenylene)<jats:sub>2<\/jats:sub> (Ni<jats:sub>3<\/jats:sub>(HITP)<jats:sub>2<\/jats:sub>) uniformly over a large\u2010area in a high\u2010throughput manner with thickness controllability down to tens of nanometers. The MASS\u2010PRC process utilizes: 1) a micromixer\u2010embedded blade to simultaneously mix and continuously supply the metal\u2013ligand solution toward the drying front during solution shearing to generate an amorphous thin\u2010film, followed by: 2) immersion in amine solution for rapid directional crystal growth. The as\u2010synthesized c\u2010MOF film has transparency of up to 88.8% and conductivity as high as 37.1 S cm<jats:sup>\u22121<\/jats:sup>. The high uniformity in conductivity is confirmed over a 3500 mm<jats:sup>2<\/jats:sup> area with an arithmetic mean roughness (<jats:italic>R<\/jats:italic><jats:sub>a<\/jats:sub>) of 4.78\u00a0nm. The flexible thin\u2010film demonstrates the highest level of transparency for Ni<jats:sub>3<\/jats:sub>(HITP)<jats:sub>2<\/jats:sub> and the highest hydrogen sulfide (H<jats:sub>2<\/jats:sub>S) sensing performance (2,085% at 5\u00a0ppm) among c\u2010MOFs\u2010based H<jats:sub>2<\/jats:sub>S sensors, enabling wearable gas\u2010sensing applications.<\/jats:p>","DOI":"10.1002\/adma.202107696","type":"journal-article","created":{"date-parts":[[2022,1,18]],"date-time":"2022-01-18T06:35:07Z","timestamp":1642487707000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":80,"title":["Large\u2010Area Synthesis of Ultrathin, Flexible, and Transparent Conductive Metal\u2013Organic Framework Thin Films via a Microfluidic\u2010Based Solution Shearing Process"],"prefix":"10.1002","volume":"34","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-0092-6164","authenticated-orcid":false,"given":"Taehoon","family":"Lee","sequence":"first","affiliation":[{"name":"Department of Materials Science and Engineering Korea Advanced Institute of Science and Technology (KAIST)  Daejeon 34141 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3322-7100","authenticated-orcid":false,"given":"Jin\u2010Oh","family":"Kim","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering Korea Advanced Institute of Science and Technology (KAIST)  Daejeon 34141 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chungseong","family":"Park","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering Korea Advanced Institute of Science and Technology (KAIST)  Daejeon 34141 Republic of 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Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Siyoung Q.","family":"Choi","sequence":"additional","affiliation":[{"name":"KAIST Institute for the NanoCentury Department of Chemical and Biomolecular Engineering Korea Advanced Institute of Science and Technology (KAIST)  Daejeon 34141 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Il\u2010Doo","family":"Kim","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering Korea Advanced Institute of Science and Technology (KAIST)  Daejeon 34141 Republic of Korea"},{"name":"Membrane Innovation Center for Anti\u2010Virus &amp; Air\u2010Quality Control KAIST Institute for Nanocentury  Daejeon 34141 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1428-592X","authenticated-orcid":false,"given":"Steve","family":"Park","sequence":"additional","affiliation":[{"name":"Department of Materials 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