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However, it is challenging to achieve stable electrochemical performances using a traditional microsized silicon anode due to the poor electrical conductivity, serious volume expansion, and unstable solid electrolyte interface. Herein, a composite microsized Si anode is designed and synthesized by constructing a unique polymer, poly(hexaazatrinaphthalene) (PHATN), at a Si\/C surface (PCSi). The Li\n                    <jats:sup>+<\/jats:sup>\n                    transport mechanism of the PCSi is elucidated by using in situ characterization and theoretical simulation. During the lithiation of the PCSi anode, \uf8ffC\uf8feN\uf8ff groups with high electron density in the PHATN first coordinate Li\n                    <jats:sup>+<\/jats:sup>\n                    to form \uf8ffC\uf8ffN\uf8ffLi bonds on both sides of the PHATN molecule plane. Consequently, the original benzene rings in the PHATN become active centers to accept lithium and form stable Li\u2010rich PHATN coatings. PHATN molecules expand due to the change of molecular configuration during the consecutive lithiation process, which provides controllable space for the volume expansion of the Si particles. The PCSi composite anode exhibits a specific capacity of 1129.6 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    after 500 cycles at 1 A g\n                    <jats:sup>\u22121<\/jats:sup>\n                    , and exhibits compelling rate performance, maintaining 417.9 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 16.5 A g\n                    <jats:sup>\u22121<\/jats:sup>\n                    .\n                  <\/jats:p>","DOI":"10.1002\/adma.202109658","type":"journal-article","created":{"date-parts":[[2022,2,16]],"date-time":"2022-02-16T12:18:51Z","timestamp":1645013931000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":194,"title":["High\u2010Performance Microsized Si Anodes for Lithium\u2010Ion Batteries: Insights into the Polymer Configuration Conversion Mechanism"],"prefix":"10.1002","volume":"34","author":[{"given":"Qiyu","family":"Wang","sequence":"first","affiliation":[{"name":"Research Center of Nano Science and Technology Department of Chemistry College of Sciences Shanghai University  Shanghai 200444 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Meng","family":"Zhu","sequence":"additional","affiliation":[{"name":"Research Center of Nano Science and Technology Department of Chemistry College of Sciences Shanghai University  Shanghai 200444 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guorong","family":"Chen","sequence":"additional","affiliation":[{"name":"Research Center of Nano Science and Technology Department of Chemistry College of Sciences Shanghai University  Shanghai 200444 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Natalia","family":"Dudko","sequence":"additional","affiliation":[{"name":"Head of the Inter\u2010University R&amp;D Marketing 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