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Perovskite ferroelectric semiconductors incorporating chirality provide new opportunities in dealing with this issue. Herein, a pair of 2D chiral perovskite ferroelectrics is reported, which have\u00a0enhanced CPL detection performance due to interplays among lattice, photon, charge, spin, and orbit. The chirality\u2010transfer\u2010induced chiral&amp;polar ferroelectric phase enhances the asymmetric nature of the photoactive sublattice and achieves a switchable self\u2010powered detection via the bulk photovoltaic effect. The single\u2010crystal\u2010based device exhibits a CPL\u2010sensitive detection performance under 430\u00a0nm with an asymmetric factor of 0.20 for left\u2010 and right\u2010CPL differentiation, about two times that of the pure chiral counterparts. The enhanced CPL detection performance is ascribed to the Rashba\u2013Dresselhaus effect that originates from the bulk inversion asymmetry and strong spin\u2013orbit coupling, shown with a large Rashba coefficient, which is demonstrated by density functional theory calculation and circularly polarized light excited photoluminescence measurement. These results provide new perspectives on chiral Rashba ferroelectric semiconductors for direct CPL detection and ferroelectrics\u2010based chiroptics and spintronics.<\/jats:p>","DOI":"10.1002\/adma.202204119","type":"journal-article","created":{"date-parts":[[2022,9,21]],"date-time":"2022-09-21T01:34:15Z","timestamp":1663724055000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":177,"title":["Chiral Rashba Ferroelectrics for Circularly Polarized Light Detection"],"prefix":"10.1002","volume":"34","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-1660-2906","authenticated-orcid":false,"given":"Chang\u2010Chun","family":"Fan","sequence":"first","affiliation":[{"name":"Jiangsu Key Laboratory for Science and Applications of Molecular Ferroelectrics, School of Chemistry and Chemical Engineering Southeast University  Nanjing Jiangsu 211189 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