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However, studies of cuprous hydroxide (CuOH) have been scarce due to structural metastability. Herein, a facile, wet\u2010chemistry procedure is reported for the preparation of stable CuOH nanostructures via deliberate functionalization with select organic ligands, such as acetylene and mercapto derivatives. The resulting nanostructures are found to exhibit a nanoribbon morphology consisting of small nanocrystals embedded within a largely amorphous nanosheet\u2010like scaffold. The acetylene derivatives are found to anchor onto the CuOH forming Cu\uf8ffC\uf8fd linkages, whereas Cu\uf8ffS\uf8ff interfacial bonds are formed with the mercapto ligands. Effective electronic coupling occurs at the ligand\u2010core interface in the former, in contrast to mostly non\u2010conjugated interfacial bonds in the latter, as manifested in spectroscopic measurements and confirmed in theoretical studies based on first principles calculations. Notably, the acetylene\u2010capped CuOH nanostructures exhibit markedly enhanced photodynamic activity in the inhibition of bacteria growth, as compared to the mercapto\u2010capped counterparts due to a reduced material bandgap and effective photocatalytic generation of reactive oxygen species. Results from this study demonstrate that deliberate structural engineering with select organic ligands is an effective strategy in the stabilization and functionalization of CuOH nanostructures, a critical first step in exploring their diverse applications.<\/jats:p>","DOI":"10.1002\/adma.202208665","type":"journal-article","created":{"date-parts":[[2022,12,3]],"date-time":"2022-12-03T16:46:15Z","timestamp":1670085975000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":9,"title":["Stable Cuprous Hydroxide Nanostructures by Organic Ligand Functionalization"],"prefix":"10.1002","volume":"35","author":[{"given":"Qiming","family":"Liu","sequence":"first","affiliation":[{"name":"Department of Chemistry and Biochemistry University of California  1156 High Street Santa Cruz CA 95064 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yi","family":"Peng","sequence":"additional","affiliation":[{"name":"Department of 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