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However, the major drawbacks of Li metal, such as high reactivity and large volume expansion, can lead to dendrite growth and solid electrolyte interface (SEI) fracture. An in situ artificial inorganic SEI layer, consisting of lithium nitride and lithium sulfide, is herein reported to address the dendrite growth issues. Porous graphene oxide films are doped with sulfur and nitrogen (denoted as SNGO) to work as an effective lithium host. The SNGO film enables the in situ formation of an inorganic\u2010rich SEI layer, which facilitates the transport of Li\u2010ions, improves SEI mechanical strength, and avoids SEI fracture. In addition, COMSOL simulation results reveal that the microchannels fabricated by the 3D printing technique further shorten the Li\u2010ion transfer pathways and homogenize heat and stress distribution in the batteries. As a result, the assembled anode shows low capacity fading of 0.1% per cycle at 2 C rate with the sulfur cathode. In addition, the high lithium utilization of the SNGO host enables the anode to provide a stable capacity at low negative\/positive electrode ratios under 3 in Li\uf8ffS batteries.<\/jats:p>","DOI":"10.1002\/adma.202209028","type":"journal-article","created":{"date-parts":[[2022,12,8]],"date-time":"2022-12-08T16:59:41Z","timestamp":1670518781000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":149,"title":["A 3D Framework with Li\n                    <sub>3<\/sub>\n                    N\u2013Li\n                    <sub>2<\/sub>\n                    S Solid Electrolyte Interphase and Fast Ion Transfer Channels for a Stabilized Lithium\u2010Metal Anode"],"prefix":"10.1002","volume":"35","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-8787-2618","authenticated-orcid":false,"given":"Shuyan","family":"Ni","sequence":"first","affiliation":[{"name":"Tsinghua\u2010Berkeley Shenzhen Institute &amp; Tsinghua Shenzhen International 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