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As the simplest zinc compounds, zinc chalcogenides, and halides are individually applied as a Zn protection layer due to high zinc ion conductivity. However, the mixed\u2010anion compounds are not studied, which constrains the Zn\n                    <jats:sup>2+<\/jats:sup>\n                    diffusion in single\u2010anion lattices to their own limits. A heteroanionic zinc ion conductor (Zn\n                    <jats:italic>\n                      <jats:sub>y<\/jats:sub>\n                    <\/jats:italic>\n                    O\n                    <jats:sub>1\u2212<\/jats:sub>\n                    <jats:italic>\n                      <jats:sub>x<\/jats:sub>\n                    <\/jats:italic>\n                    F\n                    <jats:italic>\n                      <jats:sub>x<\/jats:sub>\n                    <\/jats:italic>\n                    ) coating layer is designed by in situ growth method with tunable F content and thickness. Strengthened by F aliovalent doping, the Zn\n                    <jats:sup>2+<\/jats:sup>\n                    conductivity is enhanced within the wurtzite motif for rapid lattice Zn migration. Zn\n                    <jats:italic>\n                      <jats:sub>y<\/jats:sub>\n                    <\/jats:italic>\n                    O\n                    <jats:sub>1\u2212<\/jats:sub>\n                    <jats:italic>\n                      <jats:sub>x<\/jats:sub>\n                    <\/jats:italic>\n                    F\n                    <jats:italic>\n                      <jats:sub>x<\/jats:sub>\n                    <\/jats:italic>\n                    also affords zincophilic sites for oriented superficial Zn plating to suppress dendrite growth. Therefore, Zn\n                    <jats:italic>\n                      <jats:sub>y<\/jats:sub>\n                    <\/jats:italic>\n                    O\n                    <jats:sub>1\u2212<\/jats:sub>\n                    <jats:italic>\n                      <jats:sub>x<\/jats:sub>\n                    <\/jats:italic>\n                    F\n                    <jats:italic>\n                      <jats:sub>x<\/jats:sub>\n                    <\/jats:italic>\n                    \u2010coated anode exhibits a low overpotential of 20.4\u00a0mV for 1000\u00a0h cycle life at a plating capacity of 1.0\u00a0mA\u00a0h\u00a0cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    during symmetrical cell test. The MnO\n                    <jats:sub>2<\/jats:sub>\n                    \/\/Zn full battery further proves high stability of 169.7 mA\u00a0h\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    for 1000 cycles. This work may enlighten the mixed\u2010anion tuning for high\u2010performance Zn\u2010based energy storage devices.\n                  <\/jats:p>","DOI":"10.1002\/adma.202300195","type":"journal-article","created":{"date-parts":[[2023,2,22]],"date-time":"2023-02-22T21:35:09Z","timestamp":1677101709000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":94,"title":["A Heteroanionic Zinc Ion Conductor for Dendrite\u2010Free Zn Metal Anodes"],"prefix":"10.1002","volume":"35","author":[{"given":"Siwei","family":"Zhao","sequence":"first","affiliation":[{"name":"Beijing National Laboratory for Molecular Sciences and State Key Laboratory of Rare Earth Materials Chemistry and Applications College of Chemistry and Molecular Engineering Peking University  Beijing 100871 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yujing","family":"Zhang","sequence":"additional","affiliation":[{"name":"Beijing National Laboratory for Molecular Sciences College of Chemistry and Molecular Engineering Peking University  Beijing 100871 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jidao","family":"Li","sequence":"additional","affiliation":[{"name":"College of Chemical Engineering Fuzhou University  Fuzhou 350116 P. R. China"},{"name":"Laboratory of Theoretical and Computational Nanoscience CAS Center for Excellence in Nanoscience National Center for Nanoscience and Technology Chinese Academy of Sciences  Beijing 100871 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Limin","family":"Qi","sequence":"additional","affiliation":[{"name":"Beijing National Laboratory for Molecular Sciences College of Chemistry and Molecular Engineering Peking University  Beijing 100871 P. R. 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