{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,7]],"date-time":"2026-10-07T18:48:20Z","timestamp":1791398900690,"version":"4.3.3"},"reference-count":63,"publisher":"Wiley","issue":"36","license":[{"start":{"date-parts":[[2023,7,20]],"date-time":"2023-07-20T00:00:00Z","timestamp":1689811200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21875039"],"award-info":[{"award-number":["21875039"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Materials"],"published-print":{"date-parts":[[2023,9]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    The sluggish kinetics of oxygen reduction reaction (ORR) and unsatisfactory durability of Pt\u2010based catalysts are severely hindering the commercialization of proton\u2010exchange\u2010membrane fuel cells (PEMFCs). In this work, the lattice compressive strain of Pt\u2010skins imposed by Pt\u2010based intermetallic cores is tailored for highly effective ORR through the confinement effect of the activated nitrogen\u2010doped porous carbon (a\u2010NPC). The modulated pores of a\u2010NPC not only promote Pt\u2010based intermetallics with ultrasmall size (average size of &lt;4\u00a0nm), but also efficiently stabilizes intermetallic nanoparticles\u00a0and sufficient exposure of active sites during the ORR process. The optimized catalyst (L1\n                    <jats:sub>2<\/jats:sub>\n                    \u2010Pt\n                    <jats:sub>3<\/jats:sub>\n                    Co@ML\u2010Pt\/NPC\n                    <jats:sub>10<\/jats:sub>\n                    ) achieves excellent mass activity (1.72 A mg\n                    <jats:sub>Pt<\/jats:sub>\n                    <jats:sup>\u22121<\/jats:sup>\n                    ) and specific activity (3.49\u00a0mA cm\n                    <jats:sub>Pt<\/jats:sub>\n                    <jats:sup>\u22122<\/jats:sup>\n                    ), which are 11\u2010 and 15\u2010fold that of commercial Pt\/C, respectively. Besides, owing to the confinement effect of a\u2010NPC and protection of Pt\u2010skins, L1\n                    <jats:sub>2<\/jats:sub>\n                    \u2010Pt\n                    <jats:sub>3<\/jats:sub>\n                    Co@ML\u2010Pt\/NPC\n                    <jats:sub>10<\/jats:sub>\n                    retains 98.1% mass activity after 30\u00a0000 cycles, and even 95% for 100\u00a0000 cycles, while Pt\/C retains only 51.2% for 30\u00a0000 cycles. Rationalized by density functional theory, compared with other metals (Cr, Mn, Fe, and Zn), L1\n                    <jats:sub>2<\/jats:sub>\n                    \u2010Pt\n                    <jats:sub>3<\/jats:sub>\n                    Co closer to the top of \u201cvolcano\u201d induces a more suitable compressive strain and electronic structure on Pt\u2010skin, leading to an optimal oxygen adsorption energy and a remarkable ORR performance.\n                  <\/jats:p>","DOI":"10.1002\/adma.202301310","type":"journal-article","created":{"date-parts":[[2023,5,17]],"date-time":"2023-05-17T15:29:25Z","timestamp":1684337365000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":119,"title":["Tailored Lattice Compressive Strain of Pt\u2010Skins by the L1\n                    <sub>2<\/sub>\n                    \u2010Pt\n                    <sub>3<\/sub>\n                    M Intermetallic Core for Highly Efficient Oxygen Reduction"],"prefix":"10.1002","volume":"35","author":[{"given":"Zichen","family":"Wang","sequence":"first","affiliation":[{"name":"College of Materials Science and Engineering Fuzhou University  Fuzhou 350108 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Suhao","family":"Chen","sequence":"additional","affiliation":[{"name":"College of Materials Science and Engineering Fuzhou University  Fuzhou 350108 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wei","family":"Wu","sequence":"additional","affiliation":[{"name":"College of Materials Science and Engineering Fuzhou University  Fuzhou 350108 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Runzhe","family":"Chen","sequence":"additional","affiliation":[{"name":"College of Materials Science and Engineering Fuzhou University  Fuzhou 350108 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yu","family":"Zhu","sequence":"additional","affiliation":[{"name":"College of Materials Science and Engineering Fuzhou University  Fuzhou 350108 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Haoran","family":"Jiang","sequence":"additional","affiliation":[{"name":"College of Materials Science and Engineering Fuzhou University  Fuzhou 350108 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Liyue","family":"Yu","sequence":"additional","affiliation":[{"name":"College of Materials Science and Engineering Fuzhou University  Fuzhou 350108 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6358-5515","authenticated-orcid":false,"given":"Niancai","family":"Cheng","sequence":"additional","affiliation":[{"name":"College of Materials Science and Engineering Fuzhou University  Fuzhou 350108 P. R. China"},{"name":"Key Laboratory of Fuel Cell Technology of Guangdong Province  Guangzhou 510641 P. R. 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