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Herein, a multi\u2010function integrating nanocatalyst, Pt\u2010containing magnetic yolk\u2010shell carbonaceous structure, having catalysis function, microenvironment heating, thermal\u00a0insulation, and elevated pressure into a whole is designed, which induces selective hydrogenation within heating\u2010constrained nanoreactors surrounded by ambient environment.\u00a0As a demonstration, carbonyl of\n                    <jats:italic>\u03b1<\/jats:italic>\n                    ,\n                    <jats:italic>\u03b2<\/jats:italic>\n                    \u2010unsaturated aldehydes\/ketones are selectively hydrogenated to unsaturated alcohols with a &gt;98% selectivity at a nearly complete conversion under mild conditions of 40\u00a0\u00b0C and 3\u00a0bar instead of harsh requirements of 120\u00a0\u00b0C and 30\u00a0bar. It is creatively demonstrated that the locally increased temperature and endogenous pressure (estimated as \u2248120\u00a0\u00b0C, 9.7\u00a0bar) in the nano\u2010sized space greatly facilitate the reaction kinetics under an alternating magnetic field. The outward\u2010diffused products to the \u201ccool environment\u201d remain thermodynamically stable, avoiding the over\u2010hydrogenation that often occurs under constantly heated conditions of 120\u00a0\u00b0C. Regulation of the electronic state of Pt by sulfur doping of carbon allows selective chemical adsorption of the \uf8ffC\uf8feO group and consequently leads to selective hydrogenation. It is expected that such a multi\u2010function integrated catalyst provides an ideal platform for precisely operating a variety of organic liquid\u2010phase transformations under mild reaction conditions.\n                  <\/jats:p>","DOI":"10.1002\/adma.202302793","type":"journal-article","created":{"date-parts":[[2023,5,20]],"date-time":"2023-05-20T02:10:27Z","timestamp":1684548627000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":28,"title":["Nanoengineered Design of inside\u2010Heating Hot Nanoreactor Surrounded by Cool Environment for Selective Hydrogenations"],"prefix":"10.1002","volume":"35","author":[{"given":"Rui\u2010Ping","family":"Zhang","sequence":"first","affiliation":[{"name":"State Key Laboratory of Fine Chemicals Liaoning Key Laboratory for Catalytic Conversion of Carbon Resources School of Chemical Engineering Dalian University of Technology  Dalian 116024 P. R. 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