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Herein, a variety of cellulose derivatives with 1,4\u2010dihydropyridine (DHP) rings are synthesized through the Hantzsch reaction, giving impressive RTP with a long lifetime of up to 1251\u00a0ms. Specifically, the introduction of acetoacetyl groups and DHP rings promotes the spin\u2010orbit coupling and intersystem crossing process; and multiple interactions between cellulose induce clustering and inhibit the nonradiative transitions, boosting long\u2010live RTP. Furthermore, the resulting transparent and flexible cellulose films also exhibit excitation\u2010dependent and color\u2010tunable afterglows by introducing different extended aromatic groups. More interestingly, the RTP performance of these films is sensitive to water and can be repeated in response to wet\/dry stimuli. Inspired by these advantages, the RTP cellulose demonstrates advanced applications in information encryption and anti\u2010counterfeiting. This work not only enriches the photophysical properties of cellulose but also provides a versatile platform for the development of sustainable afterglows.<\/jats:p>","DOI":"10.1002\/adma.202304032","type":"journal-article","created":{"date-parts":[[2023,7,28]],"date-time":"2023-07-28T01:43:40Z","timestamp":1690508620000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":107,"title":["Color\u2010Tunable, Excitation\u2010Dependent, and Water Stimulus\u2010Responsive Room\u2010Temperature Phosphorescence Cellulose for Versatile Applications"],"prefix":"10.1002","volume":"35","author":[{"given":"Fang","family":"Peng","sequence":"first","affiliation":[{"name":"State Key Laboratory of Pulp and Paper Engineering South China University of Technology  Guangzhou 510641 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yian","family":"Chen","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Pulp and Paper Engineering South China University of Technology  Guangzhou 510641 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hongchen","family":"Liu","sequence":"additional","affiliation":[{"name":"College of Textiles Zhongyuan University of Technology  Zhengzhou 450007 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Pan","family":"Chen","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering Beijing Institute of Technology  Beijing 100081 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Feng","family":"Peng","sequence":"additional","affiliation":[{"name":"Beijing Key Laboratory of Lignocellulosic Chemistry, State Key Laboratory of Efficient Production of Forest Resources Beijing Forestry University  Beijing 100083 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7493-3573","authenticated-orcid":false,"given":"Haisong","family":"Qi","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Pulp and Paper Engineering South China University of Technology  Guangzhou 510641 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2023,10,15]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202203534"},{"key":"e_1_2_8_1_2","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202104514"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.carbon.2021.05.023"},{"key":"e_1_2_8_2_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2021.131607"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202207985"},{"key":"e_1_2_8_3_2","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202208895"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.3389\/fchem.2019.00305"},{"key":"e_1_2_8_4_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-018-05298-y"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41578-020-0223-z"},{"key":"e_1_2_8_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.0c00556"},{"key":"e_1_2_8_6_1","volume":"9","author":"Xu Q. 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