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In this work, a series of di\u2010copper\u2010substituted phosphotungstatebased foams (PW<jats:sub>10<\/jats:sub>Cu<jats:sub>2<\/jats:sub>@CMC) are fabricated with tunable loadings (17 to 44\u00a0wt%), which can be successfully applied in indirect electrocatalytic syntheses of sulfenamides and disulfides. Specifically, the optimal PW<jats:sub>10<\/jats:sub>Cu<jats:sub>2<\/jats:sub>@CMC (44\u00a0wt%) exhibits excellent electrocatalytic performance for the construction of S\u2500N\/S\u2500S bonds (yields up to 99%) coupling with the efficient production of H<jats:sub>2<\/jats:sub> (\u224850\u00a0\u00b5mol\u00a0g<jats:sup>\u22121<\/jats:sup>\u00a0h<jats:sup>\u22121<\/jats:sup>). Remarkably, it enables the scale\u2010up production (\u224814.4\u00a0g in a batch experiment) and the obtained products can serve as rubber vulcanization accelerators with superior properties to traditional industrial rubber additives in real industrial processes. This powerful catalysis system that can simultaneously produce rubber vulcanization accelerator and H<jats:sub>2<\/jats:sub> may inaugurate a new electrocatalytic avenue to explore polyoxometalate\u2010based foam catalysts in electrocatalysis field.<\/jats:p>","DOI":"10.1002\/adma.202304716","type":"journal-article","created":{"date-parts":[[2023,7,1]],"date-time":"2023-07-01T03:53:45Z","timestamp":1688183625000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":86,"title":["Indirect Electrocatalysis S\u2500N\/S\u2500S Bond Construction by Robust Polyoxometalate Based Foams"],"prefix":"10.1002","volume":"35","author":[{"given":"Gang","family":"Liu","sequence":"first","affiliation":[{"name":"Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology School of Chemistry &amp; Chemical Engineering Liaocheng University  Liaocheng Shandong 252059 P. R. 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