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Production of chemicals via single\u2010atom catalysis is an attractive proposition due to its remarkable selectivity and high atomic efficiency. In this work, a supramolecular\u2010controlled pyrolysis strategy is employed to fabricate a palladium single\u2010atom (Pd<jats:sub>1<\/jats:sub>\/BNC) catalyst with B\u2010doped Pd\u2010N<jats:italic><jats:sub>x<\/jats:sub><\/jats:italic> atomic configuration. Owing to the meticulously tailored local coordination microenvironment, the as\u2010synthesized Pd<jats:sub>1<\/jats:sub>\/BNC catalyst exhibits remarkable conversion capability for a wide range of biomass\u2010derived aldehydes\/ketones. Thorough characterizations and density functional theory calculations reveal that the highly polar metal\u2010N\u2010B site, formed between the central Pd single atom and its adjacent N and B atoms, promotes hydrogen activation from the donor (reductants) and hydrogen transfer to the acceptor (C\u2550O group), consequently leading to exceptional selectivity. This system can be further extended to directly synthesize various aromatic and furonic amines from renewable lignocellulosic biomass, with their greenhouse gas emission potentials being negative in comparison to those of fossil\u2010fuel resource\u2010based amines. This research presents a highly effective and sustainable methodology for constructing C\u2500N bonds, enabling the production of a diverse array of amines from carbon\u2010neutral biomass resources.<\/jats:p>","DOI":"10.1002\/adma.202305924","type":"journal-article","created":{"date-parts":[[2023,9,12]],"date-time":"2023-09-12T09:52:41Z","timestamp":1694512361000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":42,"title":["Engineering of Local Coordination Microenvironment in Single\u2010Atom Catalysts Enabling Sustainable Conversion of Biomass into a Broad Range of Amines"],"prefix":"10.1002","volume":"36","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-5696-1180","authenticated-orcid":false,"given":"Wu\u2010Jun","family":"Liu","sequence":"first","affiliation":[{"name":"CAS Key Laboratory of Urban Pollutant Conversion Department of Environmental Science and Engineering University of Science and Technology of China  Hefei 230026 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiao","family":"Zhou","sequence":"additional","affiliation":[{"name":"CAS Key Laboratory of Urban Pollutant Conversion Department of Environmental Science and Engineering University of Science and Technology of China  Hefei 230026 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuan","family":"Min","sequence":"additional","affiliation":[{"name":"CAS Key Laboratory of Urban Pollutant Conversion Department of Environmental Science and Engineering University of Science and Technology of China  Hefei 230026 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jia\u2010Wei","family":"Huang","sequence":"additional","affiliation":[{"name":"CAS Key Laboratory of Urban Pollutant Conversion Department of Environmental Science and Engineering University of Science and Technology of China  Hefei 230026 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jie\u2010Jie","family":"Chen","sequence":"additional","affiliation":[{"name":"CAS Key Laboratory of Urban Pollutant Conversion Department of Environmental Science and Engineering University of Science and Technology of China  Hefei 230026 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuen","family":"Wu","sequence":"additional","affiliation":[{"name":"Department of Applied Chemistry University of Science and Technology of China  Hefei 230026 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Han\u2010Qing","family":"Yu","sequence":"additional","affiliation":[{"name":"CAS Key Laboratory of Urban Pollutant Conversion Department of Environmental Science and Engineering University of Science and Technology of China  Hefei 230026 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2023,11,23]]},"reference":[{"key":"e_1_2_10_1_1","volume-title":"Amines: Synthesis, Properties and Applications","author":"Lawrence S. 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