{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,6]],"date-time":"2026-10-06T15:01:14Z","timestamp":1791298874172,"version":"4.1.0"},"reference-count":62,"publisher":"Wiley","issue":"2","license":[{"start":{"date-parts":[[2023,11,30]],"date-time":"2023-11-30T00:00:00Z","timestamp":1701302400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100002402","name":"Sun Yat-sen University","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100002402","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Materials"],"published-print":{"date-parts":[[2024,1]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    The cycling instability of metallic Zn anodes hinders the practicability of aqueous Zn\u2010ion batteries, though aqueous Zn\u2010ion batteries may be the most credible alternative technology for future electrochemical energy storage applications. Commercially available trivalent chromium conversion films (TCCF) are successfully employed as robust artificial interphases on Zn metal anodes (ZMAs). Fabricated through a simple immersion method, the TCCF\u2010protected Zn (TCCF@Zn) electrode enables a superlow nucleation overpotential for Zn plating of 6.9\u00a0mV under 1\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    , outstanding Coulombic efficiency of 99.7% at 3\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    for 1600 cycles in Zn||Cu asymmetric cells and superior cyclability in symmetric Zn||Zn batteries at 0.2, 2, and 5\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    for 2500\u00a0h and 10\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    for 1200\u00a0h. More importantly, the TCCF@Zn||V\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>5<\/jats:sub>\n                    full cell exhibits a specific capacity of 118.5 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    with a retention of 53.4% at 3 A g\n                    <jats:sup>\u22121<\/jats:sup>\n                    for 3000 cycles, which is considerably larger than that of the pristine Zn||V\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>5<\/jats:sub>\n                    full cell (59.7 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    with a retention of 25.7%). This study demonstrates a highly efficient and low\u2010cost surface modification strategy derived from an industrially applicable trivalent chromium passivation technique aimed at obtaining dendrite\u2010free ZMAs with high reversibility for practical Zn batteries in the near future.\n                  <\/jats:p>","DOI":"10.1002\/adma.202306601","type":"journal-article","created":{"date-parts":[[2023,10,18]],"date-time":"2023-10-18T15:39:45Z","timestamp":1697643585000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":84,"title":["An Industrially Applicable Passivation Strategy for Significantly Improving Cyclability of Zinc Metal Anodes in Aqueous Batteries"],"prefix":"10.1002","volume":"36","author":[{"given":"Peng","family":"Wu","sequence":"first","affiliation":[{"name":"School of Chemical Engineering and Technology The Key Lab of Low\u2010Carbon Chemistry and Energy Conservation of Guangdong Province Sun Yat\u2010sen 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