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Herein, single atom Fe is implanted into TiO<jats:sub>2<\/jats:sub>\/SrTiO<jats:sub>3<\/jats:sub> (TSr) nanotube arrays by two\u2010step anodization and Sr\u2010induced crystallization. The resulting Fe\u2010TSr with both single Fe reduction centers and dominant oxidation facets (001) contributes to efficient CO<jats:sub>2<\/jats:sub> photoreduction and water oxidation for controlled production of CH<jats:sub>3<\/jats:sub>OH and CO\/CH<jats:sub>4<\/jats:sub>. The methanol yield can reach to 154.20\u00a0\u00b5mol g<jats:sub>cat<\/jats:sub><jats:sup>\u22121<\/jats:sup> h<jats:sup>\u22121<\/jats:sup> with 98.90% selectivity by immersing all the catalyst in pure water, and the yield of CO\/CH<jats:sub>4<\/jats:sub> is 147.48\u00a0\u00b5mol g<jats:sub>cat<\/jats:sub><jats:sup>\u22121<\/jats:sup> h<jats:sup>\u22121<\/jats:sup> with &gt;99.99% selectivity when the catalyst completely outside water. This CH<jats:sub>3<\/jats:sub>OH yield is 50 and 3 times higher than that of TiO<jats:sub>2<\/jats:sub> and TSr and stands among all the state\u2010of\u2010the\u2010art catalysts. The facile gas\u2013solid and gas\u2013liquid\u2013solid\u00a0phase switch can selectively control CH<jats:sub>3<\/jats:sub>OH production from \u22480% (above H<jats:sub>2<\/jats:sub>O) to 98.90% (in H<jats:sub>2<\/jats:sub>O) via slowly immersing the catalyst into water, where abundant \u2022OH and H<jats:sub>2<\/jats:sub>O around Fe sites play important role in selective CH<jats:sub>3<\/jats:sub>OH production. This work highlights a new insight for water\u2010mediated CO<jats:sub>2<\/jats:sub> photoreduction to controllably produce CH<jats:sub>3<\/jats:sub>OH.<\/jats:p>","DOI":"10.1002\/adma.202306906","type":"journal-article","created":{"date-parts":[[2023,11,8]],"date-time":"2023-11-08T06:30:26Z","timestamp":1699425026000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":49,"title":["Water\u2010Mediated Selectivity Control of CH<sub>3<\/sub>OH versus CO\/CH<sub>4<\/sub> in CO<sub>2<\/sub> Photoreduction on Single\u2010Atom Implanted Nanotube Arrays"],"prefix":"10.1002","volume":"36","author":[{"given":"Juan\u2010Ru","family":"Huang","sequence":"first","affiliation":[{"name":"Institute for New Energy Materials and Low Carbon Technologies School of Materials Science and Engineering Tianjin University of Technology  Tianjin 300384 China"},{"name":"School of Environmental Science and Engineering Tiangong University  Tianjin 300387 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