{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,23]],"date-time":"2026-10-23T23:32:02Z","timestamp":1792798322820,"version":"4.5.0"},"reference-count":60,"publisher":"Wiley","issue":"19","license":[{"start":{"date-parts":[[2024,2,13]],"date-time":"2024-02-13T00:00:00Z","timestamp":1707782400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22161142005"],"award-info":[{"award-number":["22161142005"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21975086"],"award-info":[{"award-number":["21975086"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Materials"],"published-print":{"date-parts":[[2024,5]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Hyper\u2010cross\u2010linked polymers (HCPs) with ultra\u2010high porosity, superior physicochemical stability, and excellent cost\u2010effectiveness are attractive candidates for methane storage. However, the construction of HCPs with BET surface areas exceeding 3000 m\n                    <jats:sup>2<\/jats:sup>\n                    g\n                    <jats:sup>\u22121<\/jats:sup>\n                    remains extremely challenging. In this work, a newly developed DBM\u2010knitting method with a slow\u2010knitting rate is employed to increase the cross\u2010linking degree, in which dichloromethane (DCM) is replaced by dibromomethane (DBM) as both solvent and electrophilic cross\u2010linker, resulting in highly porous and physicochemically stable HCPs. The BET surface areas of DBM\u2010knitted SHCPs\u2010Br are 44%\u2013120% higher than that of DCM\u2010knitted SHCPs\u2010Cl using the same building blocks. Remarkably, SHCP\u20103\u2010Br exhibits an unprecedentedly high porosity (\n                    <jats:italic>\n                      S\n                      <jats:sub>BET<\/jats:sub>\n                    <\/jats:italic>\n                    = 3120\u00a0m\n                    <jats:sup>2<\/jats:sup>\n                    \u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    ) among reported HCPs, and shows a competitive volumetric 5\u2013100\u00a0bar working methane capacity of 191 cm\n                    <jats:sup>3<\/jats:sup>\n                    (STP) cm\n                    <jats:sup>\u22123<\/jats:sup>\n                    at 273\u00a0K calculated by using real packing density, which outperforms sate\u2010of\u2010art metal\u2010organic framework (MOFs) at comparable conditions. This facile and versatile low\u2010knitting\u2010rate strategy enables effective improvement in the porosity of HCPs for porosity\u2010desired applications.\n                  <\/jats:p>","DOI":"10.1002\/adma.202307579","type":"journal-article","created":{"date-parts":[[2024,1,30]],"date-time":"2024-01-30T04:29:54Z","timestamp":1706588994000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":61,"title":["Dibromomethane Knitted Highly Porous Hyper\u2010Cross\u2010Linked Polymers for Efficient High\u2010Pressure Methane Storage"],"prefix":"10.1002","volume":"36","author":[{"given":"Shoukun","family":"Yang","sequence":"first","affiliation":[{"name":"Key Laboratory of Material Chemistry for Energy Conversion and Storage Ministry of Education Hubei Key Laboratory of Material Chemistry and Service Failure School of Chemistry and Chemical Engineering Huazhong University of Science and Technology  Wuhan 430074 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Conversion and Storage Ministry of Education Hubei Key Laboratory of Material Chemistry and Service Failure School of Chemistry and Chemical Engineering Huazhong University of Science and Technology  Wuhan 430074 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7181-347X","authenticated-orcid":false,"given":"Bien","family":"Tan","sequence":"additional","affiliation":[{"name":"Key Laboratory of Material Chemistry for Energy Conversion and Storage Ministry of Education Hubei Key Laboratory of Material Chemistry and Service Failure School of Chemistry and Chemical Engineering Huazhong University of Science and Technology  Wuhan 430074 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