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However, current 3D aerogels are plagued by irreconcilable contradictions between adiabatic and mechanical performance due to monotonicity of the building blocks or uncontrollable assembly behavior. Herein, a spatially confined assembly strategy of multiscale low\u2010dimensional nanocarbons is reported to decouple the stress and heat transfer. The nanofiber framework, a basis for transferring the loading strain, is covered by a continuous thin\u2010film\u2010like layer formed by the aggregation of nanoparticles, which in combination serve as the fundamental structural units for generating an elastic behavior while yielding compartments in aerogels to suppress the gaseous fluid thermal diffusion within distinct partitions. The resulting all\u2010carbon aerogels with a hierarchical cellular structure and quasi\u2010closed cell walls achieve the best thermomechanical and insulation trade\u2010off, exhibiting flyweight density (24\u00a0mg cm\n                    <jats:sup>\u22123<\/jats:sup>\n                    ), temperature\u2010constant compressibility (\u2212196\u20131600 \u00b0C), and a low thermal conductivity of 0.04\u00a0829\u00a0W m\n                    <jats:sup>\u22121<\/jats:sup>\n                    K\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 300 \u00b0C. This strategy provides a remarkable thermal protection material in hostile environments for future aerospace exploration.\n                  <\/jats:p>","DOI":"10.1002\/adma.202308519","type":"journal-article","created":{"date-parts":[[2023,11,1]],"date-time":"2023-11-01T20:18:36Z","timestamp":1698869916000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":97,"title":["Multiscale Interpenetrated\/Interconnected Network Design Confers All\u2010Carbon Aerogels with Unprecedented Thermomechanical Properties for Thermal Insulation under Extreme Environments"],"prefix":"10.1002","volume":"36","author":[{"given":"Xinyi","family":"Chang","sequence":"first","affiliation":[{"name":"Innovation Center for Textile Science and Technology College of Textiles Donghua University  Shanghai 201620 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fan","family":"Wu","sequence":"additional","affiliation":[{"name":"Innovation 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