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Herein, a synergistic strategy is developed for enhanced photothermal conversion by a greenhouse\u2010like plasmonic superstructure of 4 nm cobalt nanoparticles while maintaining their intrinsic catalytic reactivity. The silica shell plays a key role in retaining the plasmonic superstructures for efficient use of the full solar spectrum, and reducing the heat loss of cobalt nanoparticles via the nano\u2010greenhouse effect. The optimized plasmonic superstructure catalyst exhibits supra\u2010photothermal CO\n                    <jats:sub>2<\/jats:sub>\n                    methanation performance with a record\u2010high rate of 2.3 mol g\n                    <jats:sub>Co<\/jats:sub>\n                    <jats:sup>\u22121<\/jats:sup>\n                    h\n                    <jats:sup>\u22121<\/jats:sup>\n                    , close to 100% CH\n                    <jats:sub>4<\/jats:sub>\n                    selectivity, and desirable catalytic stability. This work reveals the great potential of nanoscale greenhouse effect in enhancing photothermal conversions through the combination with conventional promoting strategies, shedding light on the design of efficient photothermal nanomaterials for demanding applications.\n                  <\/jats:p>","DOI":"10.1002\/adma.202308859","type":"journal-article","created":{"date-parts":[[2023,11,6]],"date-time":"2023-11-06T16:39:30Z","timestamp":1699288770000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":76,"title":["Supra\u2010Photothermal CO\n                    <sub>2<\/sub>\n                    Methanation over Greenhouse\u2010Like Plasmonic Superstructures of Ultrasmall Cobalt Nanoparticles"],"prefix":"10.1002","volume":"36","author":[{"given":"Mujin","family":"Cai","sequence":"first","affiliation":[{"name":"Institute of Functional Nano &amp; Soft Materials (FUNSOM) Soochow University  Suzhou 215123 P. R. 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