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These materials exhibit high crystallinity and high specific surface areas of 1323 and 1114 m<jats:sup>2<\/jats:sup> g<jats:sup>\u22121<\/jats:sup>. The COFs demonstrate favorable band positions and narrow band gaps suitable for light\u2010driven applications. These advantages enable TA\u2010COFs to act as reusable metal\u2010free photocatalysts in the arylboronic acids oxidation and light\u2010induced coupling of benzylamines. In addition, these TA\u2010COFs show acid sensing capabilities, exhibiting visible and reversible color changes upon exposure to HCl\u00a0solution, HCl vapor, and NH<jats:sub>3<\/jats:sub> vapor. Further, the TA\u2010COFs outperform a wide range of previously reported COF photocathodes. The tetrazine linker in the COF skeleton represents a significant advancement in the field of COF synthesis, enhancing the separation efficiency of charge carriers during the photoreaction and contributing to their photocathodic properties. TA\u2010COFs can also degrade 5\u2010nitro\u20101,2,4\u2010triazol\u20103\u2010one (NTO), an insensitive explosive present in industrial wastewater, in 20 min in a sunlight\u2010driven photocatalytic process; thus, revealing dual functionality of the protonated TA\u2010COFs as both photodegradation and Br\u00f8nsted acid catalysts. This pioneering work opens new avenues for harnessing the potential of the tetrazine linker in COF\u2010based materials, facilitating advances in catalysis, sensing, and other related fields.<\/jats:p>","DOI":"10.1002\/adma.202311042","type":"journal-article","created":{"date-parts":[[2023,12,23]],"date-time":"2023-12-23T05:29:18Z","timestamp":1703309358000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":86,"title":["Tetrazine\u2010Linked Covalent Organic Frameworks With Acid Sensing and Photocatalytic Activity"],"prefix":"10.1002","volume":"36","author":[{"given":"Amin","family":"Zadehnazari","sequence":"first","affiliation":[{"name":"Department of Food Science College of Agricultural and Life Sciences Cornell University  Stocking Hall Ithaca NY 14853 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ahmadreza","family":"Khosropour","sequence":"additional","affiliation":[{"name":"Department of Food Science 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