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While strong interactions can facilitate fast qubit operations by all\u2010electrical control, they also provide a mechanism to couple charge noise thereby limiting qubit lifetimes. Previously believed to be negligible in bulk silicon, recent silicon nano\u2010electronic devices have shown larger than bulk spin\u2010orbit coupling strengths from Dresselhaus and Rashba couplings. Here, it is shown that with precision placement of phosphorus atoms in silicon along the [110] direction (without inversion symmetry) or [111] direction (with inversion symmetry), a wide range of Dresselhaus and Rashba coupling strength can be achieved from zero to 1113 \u00d7 10<jats:sup>\u221213<\/jats:sup>eV\u2010cm. It is shown that with precision placement of phosphorus atoms, the local symmetry (<jats:italic>C<\/jats:italic><jats:sub>2<jats:italic>v<\/jats:italic><\/jats:sub>, <jats:italic>D<\/jats:italic><jats:sub>2<jats:italic>d<\/jats:italic><\/jats:sub>, and <jats:italic>D<\/jats:italic><jats:sub>3<jats:italic>d<\/jats:italic><\/jats:sub>) can be changed to engineer spin\u2010orbit interactions. Since spin\u2010orbit interactions affect both qubit operation and lifetimes, understanding their impact is essential for quantum processor\u00a0design.<\/jats:p>","DOI":"10.1002\/adma.202312736","type":"journal-article","created":{"date-parts":[[2024,3,20]],"date-time":"2024-03-20T09:50:10Z","timestamp":1710928210000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":11,"title":["Engineering Spin\u2010Orbit Interactions in Silicon Qubits at the Atomic\u2010Scale"],"prefix":"10.1002","volume":"36","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-9232-0930","authenticated-orcid":false,"given":"Yu\u2010Ling","family":"Hsueh","sequence":"first","affiliation":[{"name":"Silicon Quantum Computing Pty Ltd. 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