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However, the reported research mainly focuses on the design of the planar configuration of OEMs and does not take into account the important influence of the spatial structure on the electrochemical properties, which seriously hamper the further performance liberation of OEMs. Herein, this work has designed a series of thioether\u2010linked naphthoquinone\u2010derived isomers with tunable spatial structures and applied them as the cathodes in AZIBs. The incomplete conjugated structure of the elaborately engineered isomers can guarantee the independence of the redox reaction of active groups, which contributes to the full utilization of active sites and high redox reversibility. In addition, the position isomerization of naphthoquinones on the benzene rings changes the zincophilic activity and redox kinetics of the isomers, signifying the importance of spatial structure on the electrochemical performance. As a result, the 2,2\u2032\u2010(1,4\u2010phenylenedithio) bis(1,4\u2010naphthoquinone) (<jats:italic>p<\/jats:italic>\u2010PNQ) with the smallest steric hindrance and the most independent redox of active sites exhibits a high specific capacity (279 mAh g<jats:sup>\u22121<\/jats:sup>), an outstanding rate capability (167 mAh g<jats:sup>\u22121<\/jats:sup> at 100 A g<jats:sup>\u22121<\/jats:sup>), and a long\u2010term cycling lifetime (over 2800\u00a0h at 0.05 A g<jats:sup>\u22121<\/jats:sup>).<\/jats:p>","DOI":"10.1002\/adma.202313388","type":"journal-article","created":{"date-parts":[[2024,2,13]],"date-time":"2024-02-13T19:24:40Z","timestamp":1707852280000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":37,"title":["Spatial Structure Design of Thioether\u2010Linked Naphthoquinone Cathodes for High\u2010Performance Aqueous Zinc\u2013Organic Batteries"],"prefix":"10.1002","volume":"36","author":[{"given":"Qi\u2010Qi","family":"Sun","sequence":"first","affiliation":[{"name":"National &amp; Local United Engineering Laboratory for Power Battery Department of Chemistry Northeast Normal University Changchun Jilin 130024 China"},{"name":"State Key Laboratory of Rare Earth Resource Utilization Changchun Institute of Applied Chemistry Chinese Academy of Sciences  Changchun 130022 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jia\u2010Yi","family":"Du","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Rare Earth Resource Utilization Changchun Institute of Applied Chemistry Chinese Academy of Sciences  Changchun 130022 China"},{"name":"School of Applied Chemistry and Engineering University of Science and Technology of China  Hefei 230026 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tao","family":"Sun","sequence":"additional","affiliation":[{"name":"Institute of Quantum and Sustainable Technology School of Chemistry and Chemical Engineering Jiangsu University  Zhenjiang 212013 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhen\u2010Bang","family":"Zhuang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Rare Earth Resource Utilization Changchun Institute of Applied Chemistry Chinese Academy of Sciences  Changchun 130022 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zi\u2010Long","family":"Xie","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Rare Earth Resource Utilization Changchun Institute of Applied Chemistry Chinese Academy of Sciences  Changchun 130022 China"},{"name":"School of Applied Chemistry and Engineering University of Science and Technology of China  Hefei 230026 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hai\u2010Ming","family":"Xie","sequence":"additional","affiliation":[{"name":"National &amp; Local United Engineering Laboratory for Power Battery Department of Chemistry Northeast Normal University Changchun Jilin 130024 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Gang","family":"Huang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Rare Earth Resource Utilization Changchun Institute of Applied Chemistry Chinese Academy of Sciences  Changchun 130022 China"},{"name":"School of Applied Chemistry and Engineering University of Science and Technology of China  Hefei 230026 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5806-159X","authenticated-orcid":false,"given":"Xin\u2010Bo","family":"Zhang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Rare Earth Resource Utilization Changchun Institute of Applied Chemistry Chinese Academy of Sciences  Changchun 130022 China"},{"name":"School of Applied Chemistry and Engineering University of Science and Technology of China  Hefei 230026 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,3,4]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-020-0674-x"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.9b00628"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.201804760"},{"key":"e_1_2_7_4_1","volume":"28","author":"Yun X.","year":"2022","journal-title":"J. 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