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Herein, a new approach for boosting the inherent ORR activity of atomically dispersed Fe\u2212N\u2212C matrix is represented by implanting Fe\u00a0atomic clusters nearby. The as\u2010prepared catalyst delivers excellent ORR activity with half\u2010wave potentials of 0.78 and 0.90\u00a0V in acidic and alkaline solutions, respectively. The decent ORR activity can also be validated from the high\u2010performance rechargeable Zn\u2013air battery. The experiments and density functional theory calculations reveal that the electron spin\u2010state of monodispersed Fe active sites is transferred from the low spin (LS, t\n                    <jats:sub>2g<\/jats:sub>\n                    <jats:sup>6<\/jats:sup>\n                    e\n                    <jats:sub>g<\/jats:sub>\n                    <jats:sup>0<\/jats:sup>\n                    ) to the medium spin (MS, t\n                    <jats:sub>2g<\/jats:sub>\n                    <jats:sup>5<\/jats:sup>\n                    e\n                    <jats:sub>g<\/jats:sub>\n                    <jats:sup>1<\/jats:sup>\n                    ) due to the involvement of Fe atomic clusters, leading to the spin electron filling in \u03c3\u2217 orbit, by which it favors OH\n                    <jats:sup>\u2212<\/jats:sup>\n                    desorption and in turn boosts the reaction kinetics of the rate\u2010determining step. This work paves a solid way for rational design of high\u2010performance Fe\u2010based single atom catalysts through spin manipulation.\n                  <\/jats:p>","DOI":"10.1002\/adma.202400523","type":"journal-article","created":{"date-parts":[[2024,4,9]],"date-time":"2024-04-09T23:09:30Z","timestamp":1712704170000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":347,"title":["Tailoring Oxygen Reduction Reaction Kinetics of Fe\u2212N\u2212C Catalyst via Spin Manipulation for Efficient Zinc\u2013Air Batteries"],"prefix":"10.1002","volume":"36","author":[{"given":"Huiwen","family":"Zhang","sequence":"first","affiliation":[{"name":"School of Integrated Circuits Wuhan National Laboratory for Optoelectronics Huazhong University of Science and Technology  Wuhan 430074 P. R. 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