{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,1]],"date-time":"2026-10-01T13:00:22Z","timestamp":1790859622086,"version":"4.1.0"},"reference-count":31,"publisher":"Wiley","issue":"30","license":[{"start":{"date-parts":[[2024,5,22]],"date-time":"2024-05-22T00:00:00Z","timestamp":1716336000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21905198"],"award-info":[{"award-number":["21905198"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004517","name":"Tianjin University","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100004517","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Materials"],"published-print":{"date-parts":[[2024,7]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Nonporous adaptive crystals (NACs) are crystalline nonporous materials that can undergo a structural adaptive phase transformation to accommodate specific guest via porous cavity or lattice voids. Most of the NACs are based on pillararenes because of their flexible backbone and intrinsic porous structure. Here a readily prepared organic hydrochloride of 4\u2010(4\u2010(diphenylamino)phenyl)pyridin\u20101\u2010ium chloride (TPAPyH), exhibiting the solvent dimension\u2010dependent adaptive crystallinity is reported. Wherein it forms a nonporous \u03b1 crystal in a solvent with larger dimensions, while forming two porous \u03b2 and \u03b3 crystals capable of accommodating solvent molecules in solvent with small size. Furthermore, the thermal\u2010induced single\u2010crystal\u2010to\u2010single\u2010crystal (SCSC) transition from the \u03b2 to \u03b1 phase can be initiated. Upon exposure to iodine vapor or immersion in aqueous solution, the nonporous \u03b1 phase transforms to porous \u03b2 phase by adsorbing iodine molecules. Owing to the formation of trihalide anion I\n                    <jats:sub>2<\/jats:sub>\n                    Cl\u02c9 within the crystal cavity, TPAPyH exhibits remarkable performance in iodine storage, with a high uptaking capacity of 1.27 g g\n                    <jats:sup>\u22121<\/jats:sup>\n                    and elevated iodine desorption temperature of up to 110 and 82\u00a0\u00b0C following the first and second adsorption stage. The unexpected adaptivity of TPAPyH inspires the design of NACs for selective adsorption and separation of volatile compound from organic small molecules.\n                  <\/jats:p>","DOI":"10.1002\/adma.202402885","type":"journal-article","created":{"date-parts":[[2024,5,16]],"date-time":"2024-05-16T10:58:47Z","timestamp":1715857127000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":28,"title":["Solvent\u2010Responsive Nonporous Adaptive Crystals Derived from Pyridinium Hydrochloride and the Application in Iodine Adsorption"],"prefix":"10.1002","volume":"36","author":[{"given":"Yi","family":"Chen","sequence":"first","affiliation":[{"name":"Institute of Molecular Aggregation Science Tianjin University  Tianjin 300072 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaojuan","family":"Song","sequence":"additional","affiliation":[{"name":"Institute of Molecular Aggregation Science Tianjin University  Tianjin 300072 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Aisen","family":"Li","sequence":"additional","affiliation":[{"name":"Joint School of National University of Singapore and Tianjin University International Campus of Tianjin University  Binhai New City Fuzhou 350207 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ziang","family":"Song","sequence":"additional","affiliation":[{"name":"Institute of Molecular Aggregation Science Tianjin University  Tianjin 300072 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shiyao","family":"Fu","sequence":"additional","affiliation":[{"name":"Institute of Molecular Aggregation Science Tianjin University  Tianjin 300072 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yujun","family":"Xie","sequence":"additional","affiliation":[{"name":"Institute of Molecular Aggregation Science Tianjin University  Tianjin 300072 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ben Zhong","family":"Tang","sequence":"additional","affiliation":[{"name":"Institute of Molecular Aggregation Science Tianjin University  Tianjin 300072 China"},{"name":"School of Science and Engineering Shenzhen Institute of Aggregate Science and Technology The Chinese University of Hong Kong  Shenzhen 518172 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1512-1345","authenticated-orcid":false,"given":"Zhen","family":"Li","sequence":"additional","affiliation":[{"name":"Institute of Molecular Aggregation Science Tianjin University  Tianjin 300072 China"},{"name":"Joint School of National University of Singapore and Tianjin University International Campus of Tianjin University  Binhai New City Fuzhou 350207 China"},{"name":"Hubei Key Lab on Organic and Polymeric Opto\u2010Electronic Materials Department of Chemistry Wuhan University  Wuhan 430072 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,5,22]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.31635\/ccschem.021.202100968"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202013117"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1MH01360B"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1CC03287A"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-019-10575-5"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja208284t"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr300014x"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja206846p"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41563-021-01052-w"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b03204"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c03938"},{"key":"e_1_2_7_12_1","volume":"33","author":"Gu Q.","year":"2023","journal-title":"Adv. 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