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However, the redox conversion of multivalent S in ZBs is still limited, only having achieved S\n                    <jats:sup>0<\/jats:sup>\n                    \/S\n                    <jats:sup>2\u2212<\/jats:sup>\n                    redox conversion with low discharge voltage and poor reversibility. This study presents significant progress by demonstrating, for the first time, the reversible S\n                    <jats:sup>2\u2212<\/jats:sup>\n                    \/S\n                    <jats:sup>4+<\/jats:sup>\n                    redox behavior in ZBs with up to six\u2010electron transfer (with an achieved discharge capacity of \u22481284 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    ) using a highly concentrated ClO\n                    <jats:sub>4<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    \u2010containing electrolyte. The developed succinonitrile\u2013Zn(ClO\n                    <jats:sub>4<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    eutectic electrolyte stabilizes the positive\u2010valence S compound and contributes to an ultra\u2010low polarization voltage. Notably, the achieved flat discharge plateaus demonstrate the highest operation voltage (1.54\u00a0V) achieved to date in Zn\u2016S batteries. Furthermore, the high\u2010voltage Zn\u2016S battery exhibits remarkable conversion dynamics, excellent cycling performance (85.7% capacity retention after 500 cycles), high efficiency (98.4%), and energy density (527\u00a0Wh\u00a0kg\u00a0\n                    <jats:sub>S<\/jats:sub>\n                    <jats:sup>\u22121<\/jats:sup>\n                    ). This strategy of positive\u2010valence conversion of sulfur represents a significant advancement in understanding sulfur chemistry in batteries and holds promise for future high\u2010voltage sulfur\u2010based batteries.\n                  <\/jats:p>","DOI":"10.1002\/adma.202402898","type":"journal-article","created":{"date-parts":[[2024,6,11]],"date-time":"2024-06-11T22:11:34Z","timestamp":1718143894000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":45,"title":["Highly Reversible Positive\u2010Valence Conversion of Sulfur Chemistry for High\u2010Voltage Zinc\u2013Sulfur Batteries"],"prefix":"10.1002","volume":"36","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-4621-623X","authenticated-orcid":false,"given":"Ze","family":"Chen","sequence":"first","affiliation":[{"name":"Department of Materials Science and Engineering City University of Hong Kong  83 Tat Chee Avenue Kowloon Hong Kong 999077 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