{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,24]],"date-time":"2026-09-24T17:51:09Z","timestamp":1790272269140,"version":"4.1.0"},"reference-count":78,"publisher":"Wiley","issue":"26","license":[{"start":{"date-parts":[[2024,4,18]],"date-time":"2024-04-18T00:00:00Z","timestamp":1713398400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52271217"],"award-info":[{"award-number":["52271217"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52201217"],"award-info":[{"award-number":["52201217"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52130101"],"award-info":[{"award-number":["52130101"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100002858","name":"China Postdoctoral Science Foundation","doi-asserted-by":"publisher","award":["2022M711290"],"award-info":[{"award-number":["2022M711290"]}],"id":[{"id":"10.13039\/501100002858","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012226","name":"Fundamental Research Funds for the Central Universities","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100012226","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Materials"],"published-print":{"date-parts":[[2024,6]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Aqueous zinc\u2010ion batteries are attractive post\u2010lithium battery technologies for grid\u2010scale energy storage because of their inherent safety, low cost and high theoretical capacity. However, their practical implementation in wide\u2010temperature surroundings persistently confronts irregular zinc electrodeposits and parasitic side reactions on metal anode, which leads to poor rechargeability, low Coulombic efficiency and short lifespan. Here, this work reports lamellar nanoporous Cu\/Al<jats:sub>2<\/jats:sub>Cu heterostructure electrode as a promising anode host material to regulate high\u2010efficiency and dendrite\u2010free zinc electrodeposition and stripping for wide\u2010temperatures aqueous zinc\u2010ion batteries. In this unique electrode, the interconnective Cu\/Al<jats:sub>2<\/jats:sub>Cu heterostructure ligaments not only facilitate fast electron transfer but work as highly zincophilic sites for zinc nucleation and deposition by virtue of local galvanic couples while the interpenetrative lamellar channels serving as mass transport pathways. As a result, it exhibits exceptional zinc plating\/stripping behaviors in aqueous hybrid electrolyte of diethylene glycol dimethyl ether and zinc trifluoromethanesulfonate at wide temperatures ranging from 25 to \u221230\u00a0\u00b0C, with ultralow voltage polarizations at various current densities and ultralong lifespan of &gt;4000 h. The outstanding electrochemical properties enlist full cell of zinc\u2010ion batteries constructed with nanoporous Cu\/Al<jats:sub>2<\/jats:sub>Cu and Zn<jats:italic><jats:sub>x<\/jats:sub><\/jats:italic>V<jats:sub>2<\/jats:sub>O<jats:sub>5<\/jats:sub>\/C to maintain high capacity and excellent stability for &gt;5000 cycles at 25 and \u221230\u00a0\u00b0C.<\/jats:p>","DOI":"10.1002\/adma.202403803","type":"journal-article","created":{"date-parts":[[2024,4,10]],"date-time":"2024-04-10T11:20:20Z","timestamp":1712748020000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":84,"title":["Lamellar Nanoporous Metal\/Intermetallic Compound Heterostructure Regulating Dendrite\u2010Free Zinc Electrodeposition for Wide\u2010Temperature Aqueous Zinc\u2010Ion Battery"],"prefix":"10.1002","volume":"36","author":[{"given":"Huan","family":"Meng","sequence":"first","affiliation":[{"name":"Key Laboratory of Automobile Materials (Jilin University) Ministry of Education School of Materials Science and Engineering Jilin University  Changchun 130022 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qing","family":"Ran","sequence":"additional","affiliation":[{"name":"Key Laboratory of Automobile Materials (Jilin University) Ministry of Education School of Materials Science and Engineering Jilin University  Changchun 130022 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tian\u2010Yi","family":"Dai","sequence":"additional","affiliation":[{"name":"Key Laboratory of Automobile Materials (Jilin University) Ministry of Education School of Materials Science and Engineering Jilin University  Changchun 130022 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jian\u2010Hui","family":"Jia","sequence":"additional","affiliation":[{"name":"Key Laboratory of Automobile Materials (Jilin University) Ministry of Education School of Materials Science and Engineering Jilin University  Changchun 130022 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jie","family":"Liu","sequence":"additional","affiliation":[{"name":"Key Laboratory of Automobile Materials (Jilin University) Ministry of Education School of Materials Science and Engineering Jilin University  Changchun 130022 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hang","family":"Shi","sequence":"additional","affiliation":[{"name":"Key Laboratory of Automobile Materials (Jilin University) Ministry of Education School of Materials Science and Engineering Jilin University  Changchun 130022 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Gao\u2010Feng","family":"Han","sequence":"additional","affiliation":[{"name":"Key Laboratory of Automobile Materials (Jilin University) Ministry of Education School of Materials Science and Engineering Jilin University  Changchun 130022 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tong\u2010Hui","family":"Wang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Automobile Materials (Jilin University) Ministry of Education School of Materials Science and Engineering Jilin University  Changchun 130022 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zi","family":"Wen","sequence":"additional","affiliation":[{"name":"Key Laboratory of Automobile Materials (Jilin University) Ministry of Education School of Materials Science and Engineering Jilin University  Changchun 130022 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8227-9695","authenticated-orcid":false,"given":"Xing\u2010You","family":"Lang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Automobile Materials (Jilin University) Ministry of Education School of Materials Science and Engineering Jilin University  Changchun 130022 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qing","family":"Jiang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Automobile Materials (Jilin University) Ministry of Education School of Materials Science and Engineering Jilin University  Changchun 130022 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,4,18]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1212741"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.2c00289"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1038\/natrevmats.2016.13"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41563-018-0063-z"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202000162"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0EE02162H"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9EE02526J"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.8b01426"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202007548"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.9b01403"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.2c02042"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.abn5097"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c13003"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202003065"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201903778"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202207344"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202016531"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-020-18284-0"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0CC03963B"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c09794"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-41276-9"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0EE01538E"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.1c00420"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.1c04353"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3EE01741A"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1007\/s40820-022-00836-2"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2022.10.046"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.3c06687"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202210789"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2022.08.046"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202008424"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-020-15478-4"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.0c02343"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202108533"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.2c01960"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-020-17752-x"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2021.03.024"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.2c01958"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202103390"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1EE02021H"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202007416"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-021-00797-7"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aax6873"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.0c04519"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2019.02.012"},{"key":"e_1_2_8_46_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202305532"},{"key":"e_1_2_8_47_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202302353"},{"key":"e_1_2_8_48_1","doi-asserted-by":"publisher","DOI":"10.1007\/s40820-023-01304-1"},{"key":"e_1_2_8_49_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202201957"},{"key":"e_1_2_8_50_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-020-16769-6"},{"key":"e_1_2_8_51_1","doi-asserted-by":"publisher","DOI":"10.1038\/35068529"},{"key":"e_1_2_8_52_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-022-28238-3"},{"key":"e_1_2_8_53_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-018-06043-1"},{"key":"e_1_2_8_54_1","doi-asserted-by":"publisher","DOI":"10.1007\/s40820-022-00867-9"},{"key":"e_1_2_8_55_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.254.5032.687"},{"key":"e_1_2_8_56_1","doi-asserted-by":"publisher","DOI":"10.1016\/0010-938X(83)90034-3"},{"key":"e_1_2_8_57_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja02182a005"},{"key":"e_1_2_8_58_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202007388"},{"key":"e_1_2_8_59_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.1c01054"},{"key":"e_1_2_8_60_1","author":"Chen S.","year":"2022","journal-title":"Angew. Chem. Int. Ed."},{"key":"e_1_2_8_61_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-36198-5"},{"key":"e_1_2_8_62_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2022.04.032"},{"key":"e_1_2_8_63_1","doi-asserted-by":"publisher","DOI":"10.1016\/0584-8539(67)80135-1"},{"key":"e_1_2_8_64_1","doi-asserted-by":"publisher","DOI":"10.1016\/0584-8539(73)80044-3"},{"key":"e_1_2_8_65_1","doi-asserted-by":"publisher","DOI":"10.1016\/0167-2738(93)90271-4"},{"key":"e_1_2_8_66_1","doi-asserted-by":"publisher","DOI":"10.1016\/0167-2738(93)90270-D"},{"key":"e_1_2_8_67_1","doi-asserted-by":"publisher","DOI":"10.1021\/je500389t"},{"key":"e_1_2_8_68_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202105951"},{"key":"e_1_2_8_69_1","first-page":"2","volume":"6","author":"Li Q.","year":"2022","journal-title":"Joule"},{"key":"e_1_2_8_70_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.75.165202"},{"key":"e_1_2_8_71_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.matt.2023.08.019"},{"key":"e_1_2_8_72_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-020-0674-x"},{"key":"e_1_2_8_73_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201702097"},{"key":"e_1_2_8_74_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202200318"},{"key":"e_1_2_8_75_1","doi-asserted-by":"publisher","DOI":"10.1007\/s40820-022-00969-4"},{"key":"e_1_2_8_76_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202207682"},{"key":"e_1_2_8_77_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202211271"},{"key":"e_1_2_8_78_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202001263"}],"container-title":["Advanced Materials"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/adma.202403803","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,6]],"date-time":"2025-10-06T13:15:45Z","timestamp":1759756545000},"score":1,"resource":{"primary":{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/10.1002\/adma.202403803"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,4,18]]},"references-count":78,"journal-issue":{"issue":"26","published-print":{"date-parts":[[2024,6]]}},"alternative-id":["10.1002\/adma.202403803"],"URL":"https:\/\/doi.org\/10.1002\/adma.202403803","archive":["Portico"],"relation":{},"ISSN":["0935-9648","1521-4095"],"issn-type":[{"value":"0935-9648","type":"print"},{"value":"1521-4095","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024,4,18]]},"assertion":[{"value":"2024-03-14","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2024-04-18","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"2403803"}}