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Herein, the planar chlorination engineering of Fe\u2010N\n                    <jats:sub>4<\/jats:sub>\n                    site is first proposed for remarkably improving the ORR activity. The Fe\u2010N\n                    <jats:sub>4<\/jats:sub>\n                    \/CNCl catalyst with broken symmetry exhibits a half\u2010wave potential (\n                    <jats:italic>E<\/jats:italic>\n                    <jats:sub>1\/2<\/jats:sub>\n                    ) of 0.917\u00a0V versus RHE, 49 and 72\u00a0mV higher than those of traditional Fe\u2010N\n                    <jats:sub>4<\/jats:sub>\n                    \/CN and commercial 20 wt% Pt\/C catalysts. The Fe\u2010N\n                    <jats:sub>4<\/jats:sub>\n                    \/CNCl catalyst also has excellent stability for 25\u00a0000 cycles and good methanol tolerance ability. For Zn\u2010air battery test, the Fe\u2010N\n                    <jats:sub>4<\/jats:sub>\n                    \/CNCl catalyst has the maximum power density of 228\u00a0mW cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    and outstanding stability during 150\u00a0h charge\u2013discharge test, as the promising substitute of Pt\u2010based catalysts in energy storage and conversion devices. The density functional theory calculation demonstrates that the adjacent C\u2500Cl bond effectively breaks the symmetry of Fe\u2010N\n                    <jats:sub>4<\/jats:sub>\n                    site, downward shifts the d\u2010band center of Fe, facilitates the reduction and release of OH\n                    <jats:sup>*<\/jats:sup>\n                    , and remarkably lowers the energy barrier of rate\u2010determining step. This work reveals the enormous potential of planar chlorination engineering for boosting the ORR activity of traditional metal\u2010N\n                    <jats:sub>4<\/jats:sub>\n                    site by thoroughly breaking their geometric symmetry.\n                  <\/jats:p>","DOI":"10.1002\/adma.202404692","type":"journal-article","created":{"date-parts":[[2024,5,16]],"date-time":"2024-05-16T09:58:46Z","timestamp":1715853526000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":55,"title":["Planar Chlorination Engineering: A Strategy of Completely Breaking the Geometric Symmetry of Fe\u2010N\n                    <sub>4<\/sub>\n                    Site for Boosting Oxygen Electroreduction"],"prefix":"10.1002","volume":"36","author":[{"given":"Shengjie","family":"Wei","sequence":"first","affiliation":[{"name":"School of Materials Science and Engineering Nankai University  Tianjin 300350 P. R. 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