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Nonoxygenated chemicals, including light olefins, 1,3\u2010butadiene, aromatics, and gasoline, are some of the most important of these commodities, substantially contributing to modern lifestyles. Despite the industrial implementation of some ethanol\u2010to\u2010hydrocarbons processes, several fundamental questions and technological challenges remain unaddressed. In addition, the utilization of ethanol as an intermediate provides new opportunities for the direct valorization of CO and CO<jats:sub>2<\/jats:sub>. Herein, the recent advances in the design of ethanol conversion catalysts are summarized, providing mechanistic insights into the corresponding reactions and catalyst deactivation, and discussing the related future research directions, including the exploitation of active site proximity to achieve better synergistic effects for reactions involving ethanol.<\/jats:p>","DOI":"10.1002\/adma.202406472","type":"journal-article","created":{"date-parts":[[2024,9,6]],"date-time":"2024-09-06T10:09:43Z","timestamp":1725617383000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":19,"title":["Advances in the Catalytic Conversion of Ethanol into Nonoxygenated Added\u2010Value Chemicals"],"prefix":"10.1002","volume":"36","author":[{"given":"Xueli","family":"Yao","sequence":"first","affiliation":[{"name":"King Abdullah University of Science and Technology (KAUST) KAUST Catalysis Center (KCC)  Thuwal 23955 Saudi Arabia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4926-1837","authenticated-orcid":false,"given":"Teng","family":"Li","sequence":"additional","affiliation":[{"name":"King Abdullah University of Science and Technology (KAUST) KAUST Catalysis Center (KCC)  Thuwal 23955 Saudi Arabia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sang\u2010Ho","family":"Chung","sequence":"additional","affiliation":[{"name":"King Abdullah University of Science and Technology (KAUST) KAUST Catalysis Center (KCC)  Thuwal 23955 Saudi Arabia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9850-7939","authenticated-orcid":false,"given":"Javier","family":"Ruiz\u2010Mart\u00ednez","sequence":"additional","affiliation":[{"name":"King Abdullah University of Science and Technology (KAUST) KAUST Catalysis Center (KCC)  Thuwal 23955 Saudi Arabia"},{"name":"Chemical Engineering Program Physical Science and Engineering (PSE) Division King Abdullah University of Science and Technology  Thuwal 23955 Saudi Arabia"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,9,6]]},"reference":[{"key":"e_1_2_9_1_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr068360d"},{"key":"e_1_2_9_2_1","first-page":"604","volume":"338","author":"Tuck C. 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