{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,2]],"date-time":"2026-09-02T15:48:11Z","timestamp":1788364091986,"version":"build-2803163510"},"reference-count":50,"publisher":"Wiley","issue":"49","license":[{"start":{"date-parts":[[2024,10,21]],"date-time":"2024-10-21T00:00:00Z","timestamp":1729468800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc-nd\/4.0\/"},{"start":{"date-parts":[[2024,10,21]],"date-time":"2024-10-21T00:00:00Z","timestamp":1729468800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100003725","name":"National Research Foundation of Korea","doi-asserted-by":"publisher","award":["NRF\u20102021R1A5A1084921"],"award-info":[{"award-number":["NRF\u20102021R1A5A1084921"]}],"id":[{"id":"10.13039\/501100003725","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003725","name":"National Research Foundation of Korea","doi-asserted-by":"publisher","award":["RS\u20102024\u201000435493"],"award-info":[{"award-number":["RS\u20102024\u201000435493"]}],"id":[{"id":"10.13039\/501100003725","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Materials"],"published-print":{"date-parts":[[2024,12]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    The lithium\u2010mediated nitrogen reduction reaction (Li\u2010NRR) is a promising green alternative to the Haber\u2013Bosch process for ammonia synthesis. The solid electrolyte interphase (SEI) is crucial for high efficiency and stability, as it regulates reactant diffusion and suppresses side reactions. The SEI properties are greatly influenced by the Li\n                    <jats:sup>+<\/jats:sup>\n                    ion solvation structure, which is controllable through electrolyte engineering. Although anion\u2010derived SEI enhances selectivity and stability, it has typically been engineered using high\u2010concentration electrolytes (HCEs), which face mass transfer, viscosity, and cost issues. In this study, a localized high\u2010concentration electrolyte (LHCE) in the Li\u2010NRR is first introduced, enabling the formation of anion\u2010derived SEI in a low\u2010concentration electrolyte (LCE) by enhancing the Li\u2013anion coordination using an antisolvent. Among various antisolvents, 1,1,2,2\u2010tetrafluoroethyl\u20102,2,3,3\u2010tetrafluoropropyl ether (TTE) achieves the highest ammonia Faradaic efficiency (73.6 \u00b1 2.5%), more than double that of the LCE (34.3 \u00b1 2.8%) and exceeding the HCE (56.0 \u00b1 2.8%). Systematic calculations and experimental analyses show that the LHCE exhibits anion\u2010rich solvation structures and forms\u00a0thin, inorganic SEI. Moreover, the LHCE has advantages of low viscosity and high N\n                    <jats:sub>2<\/jats:sub>\n                    solubility, which facilitate mass transport. This study suggests the application of LHCE as an effective electrolyte engineering strategy to enhance the Li\u2010NRR efficiency.\n                  <\/jats:p>","DOI":"10.1002\/adma.202408280","type":"journal-article","created":{"date-parts":[[2024,10,22]],"date-time":"2024-10-22T02:20:37Z","timestamp":1729563637000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":38,"title":["Localized High\u2010Concentration Electrolyte in Li\u2010Mediated Nitrogen Reduction for Ammonia Synthesis"],"prefix":"10.1002","volume":"36","author":[{"given":"Hyeju","family":"Yun","sequence":"first","affiliation":[{"name":"Surface Chemistry Laboratory of Electronic Materials (SCHEMA) Department of Chemical Engineering Pohang University of Science and Technology (POSTECH)  Pohang 37673 South Korea"},{"name":"Research Center for Carbon\u2010zero Green Ammonia Cycling Pohang University of Science and Technology (POSTECH)  Pohang 37673 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chaeeun","family":"Lim","sequence":"additional","affiliation":[{"name":"Surface Chemistry Laboratory of Electronic Materials (SCHEMA) Department of Chemical Engineering Pohang University of Science and Technology (POSTECH)  Pohang 37673 South Korea"},{"name":"Research Center for Carbon\u2010zero Green Ammonia Cycling Pohang University of Science and Technology (POSTECH)  Pohang 37673 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Minjun","family":"Kwon","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering Korea Advanced Institute of Science and Technology (KAIST)  Daejeon 34141 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dongmin","family":"Lee","sequence":"additional","affiliation":[{"name":"Nanocatalysis and Surface Science Laboratory Department of Chemical Engineering Pohang University of Science and Technology (POSTECH)  Pohang Gyeongbuk 37673 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yongju","family":"Yun","sequence":"additional","affiliation":[{"name":"Nanocatalysis and Surface Science Laboratory Department of Chemical Engineering Pohang University of Science and Technology (POSTECH)  Pohang Gyeongbuk 37673 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dong\u2010Hwa","family":"Seo","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering Korea Advanced Institute of Science and Technology (KAIST)  Daejeon 34141 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1458-0531","authenticated-orcid":false,"given":"Kijung","family":"Yong","sequence":"additional","affiliation":[{"name":"Surface Chemistry Laboratory of Electronic Materials (SCHEMA) Department of Chemical Engineering Pohang University of 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