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However, the performance is plagued by the dissolution of intermediate polysulfides formed during conversion. Here, this issue is addressed by developing aqueous rechargeable Zn\u2010sulfurized polyacrylonitrile (SPAN) batteries using tandem catalytic systems, containing water and tetraglyme (G4) with iodine (I\n                    <jats:sub>2<\/jats:sub>\n                    ) additives. Mechanistic study and experiments reveal that the fully conjugated molecular configurations circumvent the formation of soluble polysulfides and enable reversible co\u2010storage of H\n                    <jats:sup>+<\/jats:sup>\n                    \/Zn\n                    <jats:sup>2+<\/jats:sup>\n                    with multiple redox\u2010active centers. The reduced I\n                    <jats:sub>2<\/jats:sub>\n                    by G4 activates I\n                    <jats:sup>\u2212<\/jats:sup>\n                    \/I\n                    <jats:sub>3<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    redox couple in SPAN, reducing activation energy, and accelerating Zn\u2010ion transfer kinetics. Additionally, it stabilizes the Zn anode by forming an organic\u2013inorganic interphase that induces the generation of the predominant (002) plane. The as\u2010assembled Zn\u2010SPAN batteries exhibit excellent performances, with a high capacity of 1260.4 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 0.2 A g\n                    <jats:sup>\u22121<\/jats:sup>\n                    , a high\u2010rate performance (409.3 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 5 A g\n                    <jats:sup>\u22121<\/jats:sup>\n                    ), and a long cycling stability (81.8% capacity remained over 800 cycles at 2 A g\n                    <jats:sup>\u22121<\/jats:sup>\n                    ). This work takes a crucial step forward in organosulfur compounds accompanied by multi\u2010electron transfer for the high\u2010performance aqueous zinc\u2010ion batteries.\n                  <\/jats:p>","DOI":"10.1002\/adma.202409771","type":"journal-article","created":{"date-parts":[[2024,12,11]],"date-time":"2024-12-11T03:26:29Z","timestamp":1733887589000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":33,"title":["High\u2010Capacity and Long\u2010Life Aqueous Zn\u2010SPAN Batteries with Tandem Catalysis"],"prefix":"10.1002","volume":"37","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-0211-9614","authenticated-orcid":false,"given":"Hong","family":"Li","sequence":"first","affiliation":[{"name":"Tsinghua\u2010Berkeley Shenzhen Institute &amp; Tsinghua Shenzhen International Graduate School Tsinghua University  Shenzhen 518055 China"},{"name":"Guangdong Provincial Key Laboratory of New Energy Materials Service Safety Shenzhen Key Laboratory of Energy Electrocatalytic Materials College of Materials Science and Engineering Shenzhen University  Shenzhen 518071 P. 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